IOP PUBLISHING JOURNAL OF PHYSICS A: MATHEMATICAL AND THEORETICAL J. Phys. A: Math. Theor. 40 (2007) 11923–11937 doi:10.1088/1751-8113/40/39/014 Annihilation of the electron–positron pairs in polyelectrons Alexei M Frolov and Farrukh A Chishtie Department of Applied Mathematics, University of Western Ontario, London, Ontario N6A 5B7, Canada Received 11 June 2007, in final form 14 August 2007 Published 11 September 2007 Online at stacks.iop.org/JPhysA/40/11923 Abstract Annihilation of the electron–positron pairs (or (e , e + )-pairs, for short) in various polyelectrons e + n e m = e m e + n (where n 1 and m 1) is considered. In particular, we discuss the three- and four-photon annihilation of the (e , e + )- pairs in the three-body Ps ion and four-body bi-positronium system Ps 2 . It is shown that the five-body e + 2 e 3 ion is an unbound system. The closed- form expression is derived for the amplitude-square |M| 2 of the three-photon annihilation of (e , e + )-pair at arbitrary energies of the colliding particles. Analogous amplitude-square |M| 2 for the four-photon annihilation is reduced to the form which is convenient for future analytical calculations. A method which can be used to produce macroscopic polyelectrons is briefly discussed. PACS numbers: 36.10.k, 36.10.Dr 1. Introduction Annihilation of the electron–positron pairs (or (e , e + )-pairs, for short) in various polyelectrons e + n e m is considered. The polyelectrons discussed in this work include the three-body positronium ion Ps ( e + e 2 ) and four-body bi-positronium system Ps 2 ( e + 2 e 2 ) . We also consider annihilation of the (e , e + )-pairs in macroscopic polyelectrons, i.e. in the e + n e m systems, where n N A and m N A and N A 6.022 × 10 23 is the Avogadro number. Here and everywhere, the notation e + stands for the positron, while the notation e means the electron. Theory of polyelectrons and analysis of annihilation in such systems are required in many applications. Note that in small polyelectrons e + n e m , where n 5 and m 5, the leading annihilation process is the annihilation of electron–positron pairs from bound states. In higher polyelectrons, annihilation of the (e , e + )-pairs from unbound states also contribute. The positronium ion, bi-positronium and higher polyelectrons are of great interest in some applications to astrophysics [1], solid state physics [2] and other problems [35]. Most of such applications are related to the electron–positron pair annihilation in these polyelectrons. 1751-8113/07/3911923+15$30.00 © 2007 IOP Publishing Ltd Printed in the UK 11923