Hindawi Publishing Corporation International Journal of Atmospheric Sciences Volume 2013, Article ID 503727, 26 pages http://dx.doi.org/10.1155/2013/503727 Research Article Radiation and Heat Transfer in the Atmosphere: A Comprehensive Approach on a Molecular Basis Hermann Harde Laser Engineering and Materials Science, Helmut-Schmidt-University Hamburg, Holstenhofweg 85, 22043 Hamburg, Germany Correspondence should be addressed to Hermann Harde; harde@hsu-hh.de Received 29 April 2013; Accepted 12 July 2013 Academic Editor: Shaocai Yu Copyright © 2013 Hermann Harde. his is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. We investigate the interaction of infrared active molecules in the atmosphere with their own thermal background radiation as well as with radiation from an external blackbody radiator. We show that the background radiation can be well understood only in terms of the spontaneous emission of the molecules. he radiation and heat transfer processes in the atmosphere are described by rate equations which are solved numerically for typical conditions as found in the troposphere and stratosphere, showing the conversion of heat to radiation and vice versa. Consideration of the interaction processes on a molecular scale allows to develop a comprehensive theoretical concept for the description of the radiation transfer in the atmosphere. A generalized form of the radiation transfer equation is presented, which covers both limiting cases of thin and dense atmospheres and allows a continuous transition from low to high densities, controlled by a density dependent parameter. Simulations of the up- and down-welling radiation and its interaction with the most prominent greenhouse gases water vapour, carbon dioxide, methane, and ozone in the atmosphere are presented. he radiative forcing at doubled CO 2 concentration is found to be 30% smaller than the IPCC-value. 1. Introduction Radiation processes in the atmosphere play a major role in the energy and radiation balance of the earth-atmosphere system. Downwelling radiation causes heating of the earth’s surface due to direct sunlight absorption and also due to the back radiation from the atmosphere, which is the source term of the so heavily discussed atmospheric greenhouse or atmospheric heating efect. Upward radiation contributes to cooling and ensures that the absorbed energy from the sun and the terrestrial radiation can be rendered back to space and the earth’s temperature can be stabilized. For all these processes, particularly, the interaction of radiation with infrared active molecules is of importance. hese molecules strongly absorb terrestrial radiation, emitted from the earth’s surface, and they can also be excited by some heat transfer in the atmosphere. he absorbed energy is rera- diated uniformly into the full solid angle but to some degree also re-absorbed in the atmosphere, so that the radiation underlies a continuous interaction and modiication process over the propagation distance. Although the basic relations for this interaction of radiation with molecules are already well known since the beginning of the previous century, up to now the correct application of these relations, their importance, and their consequences for the atmospheric system are discussed quite contradictorily in the community of climate sciences. herefore, it seems necessary and worthwhile to give a brief review of the main physical relations and to present on this basis a new approach for the description of the radiation transfer in the atmosphere. In Section 2, we start from Einstein’s basic quantum- theoretical considerations of radiation [1] and Planck’s radi- ation law [2] to investigate the interaction of molecules with their own thermal background radiation under the inluence of molecular collisions and at thermodynamic equilibrium [3, 4]. We show that the thermal radiation of a gas can be well understood only in terms of the spontaneous emission of the molecules. his is valid at low pressures with only few molecular collisions as well as at higher pressures and high collision rates.