© Asian Journal of Biomedical and Pharmaceutical Sciences, 2015.
Five novel spectrophotometric methods for quantitative determination of
Prulifloxacin in pure and pharmaceutical formulations
he main objective of this present work is to successfully develop one UV and four visible new spec-
trophotometric techniques. One UV and four visible spectrophotometric methods have been devel-
oped depending on the reactivity of various structural units for instance piperazine ring and tertiary
amine and carbonyl group in Pruliloxacin. It is observed that the statistical analysis results of cor-
relation coeicient of each method values are observed to be greater than 0.999 which speaks that
the proposed methods have good linearity. he order of sensitivity of the said proposed methods are
M1> M2>M5c> M5b> M5a> M4> M3. he % RSD values are observed bellow two for all methods
which shows that all the proposed methods are precise. he results of analysis of the pharmaceutical
formulations assert that the proposed methods are safely be adopted for routine quality control
of Pruliloxacin in bulk and pharmaceutical preparations to yield correct and accurate analysis re-
sults.
Keywords: Pruliloxacin, Visible spectrophotometric methods, Bratton-Marshal reagent, Validation.
ABSTRACT :
Pruliloxacin (PRFX) pertains to prodrug of uliloxacin
which is broad spectrum luoroquinolone an anti- bacterial
agent. Pruliloxacin is metabolized in the body to the
active compound in Uliloxacin. Pruliloxacin is a prodrug
and found to be efective on par with Ciproloxacin, co-
amoxiclav or Peloloxacin in the treatment of bronchitis
exacerbations and lower urinary tract infections. PRFX
is not oicial drug in IP, BP and USP pharmacopoeia.
In this connection relevant nemerous literature survey
of PRFX was compiled and thoroughly examined before
development of these methods to have adequate knowledge
in this regard. Literature survey disclosed that very few
spectrophotometric methods have been reported so far.
Majority of HPLC methods were applied in determination
of FQs in human plasma
1-5
, edible animal products, feeds
and to a lesser extent in pharmaceutical formulations
6-10
.
Capillary Zone Electrophoresis
11
methods are in existence
to determine the active metabolite of Pruliloxacin existed
in human plasma and some other biological luids. It was
also reported that there was a sensitive determination of
Pruliloxacin owing to its luorescence enhancement on
Terbium (III)-Sodium Dodecylbenzene Sulfonate system
12
.
here are no analytical reports available to estimate
PRFX for utilizing visible spectrophotometry. herefore
the author inclined to select PRFX for the development
of sensitive, precise and accurate spectrophotometric
methods validated according to ICH Q2(R1) guidelines
13
,
depending on several chemical reactions duly involving
the analytically prominent functional groups existed in
the structure. hus the author chooses one ultraviolet and
four visible spectrophotometric methods namely M
1
, M
2
,
M
3
, M
4
, and M
5a
, M
5b
, M
5c
for determination of PRFX in
bulk samples and pharmaceutical formulations. he broad
details of diferent spectrophotometric methods developed
are shown in Table 1.
*Corresponding author:
P. RAVISANKAR,
E-mail: banuman35@gmail.com
Mobile: +919000199106, +919059994000.
doi: 10.15272/ajbps.v5i48.724
INTRODUCTION:
Received on:11/07/2015
Accepted on: 25/08/2015
Published on: 15/09/2015
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Article Info:
O pen A ccess
Literati
Research Article
Panchumarthy Ravisankar
1
*
1
Department of Pharmaceutical Analysis and Quality Assurance, Vignan Pharmacy College, Vadlamudi, Guntur (Dist.) - 522213, Andhra
Pradesh, India.
1
Faculty of Science, Sri Chandrasekharendra Saraswathi Viswa Maha Vidyalaya (SCSVMV University), Enathur, Kanchipuram – 631561, T.N.,
India.
Conlict of interest: Authors reported none
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