International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 05 | May -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1306
EXPERIMENTAL STUDY OF FACTORS INFLUENCING COMPRESSIVE
STRENGTH OF GEOPOLYMER CONCRETE
Ajay Sharma
1
, Juned Ahmad
2
1
PG Student, Structural Engineering, Integral University, Uttar Pradesh, India
2
Assistant professor, Department Of Civil Engineering, Integral University, Uttar Pradesh, India
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Abstract - Manufacture of Portland cement produces large
of volumes of carbon dioxide and other gases. Releasing these
gases causes atmospheric pollution and subsequent
environmental degradation. Finding a suitable alternative
solution to mitigate the environmental degradation caused by
using Portland cement is very important for environmental
sustainability. On the other side, fly ash is the waste material
of coal based thermal power plant, available abundantly but
pose disposal problem. There are environmental benefits in
reducing the use of Portland cement in concrete, and using a
cementitious material, such as fly ash. Geopolymer concrete is
new sustainable concrete which is manufactured by replacing
cement 100% with processed fly ash which is chemically
activated by alkaline solutions made from sodium silicate
(Na2SiO3) and sodium hydroxide (NaOH). This thesis presents
the effect of several factors like alkaline liquid to fly ash ratio,
molarity of NaOH, curing hours and curing temperature on
the compressive strength of fly ash based geopolymer
concrete. Fly ash is taken as the basic material to develop the
geopolymer concrete and it is activated by the alkaline
solution of sodium silicate and sodium hydroxide. The test
variables were molarities of sodium hydroxide (NaOH) 12M,
4M, 16M, and 18M, ratio of NaOH to sodium silicate
(Na2SiO3) 2.5, alkaline liquid to fly ash ratio 0.35, 0.40, 0.45
and 0.50 were used in the present study. The experiment were
also conducted on GPC cubes for curing temperature of 75° C,
90° C and 105° C with curing period of 12, 18 and 24 hours
by adopting hot oven curing method. The test result indicated
that the compressive strength increases with increase in
molarity of NaOH but it decreases with increases in water
content. It is also absorbed that compressive strength is
remarkably affected by the curing hours and curing
temperature. When curing temperature is increases, the
compressive strength is also increases and it requires less
curing period to gain the higher strength.
1.INTRODUCTION
1.1 General
Production of cement is one of the major contributors to the
emission of green-house gasses like carbon dioxide. Day by
day the World’s Portland cement production increases with
the increasing demand of construction industry. Cement is
the main ingredient for the production of concrete. But the
production of cement requires large amount of raw
material. During the production of cement burning of lime
stone take place which results in emission of carbon dioxide
(CO2) gas into the atmosphere. There are two different
sources of CO2 emission during cement production.
Combustion of fossil fuels to operate the rotary kiln is the
largest source and other one is the chemical process of
burning limestone. In 1995 the production of cement was
1.5 billion tons which goes on increasing up to 2.2 billion
tons in 2010. One ton of production of cement causes one
ton of emission of CO2 into the atmosphere. It is estimated
that the emission of carbon dioxide due to cement
production to be nearly about 7% of the total production of
carbon dioxide, which make required to go for other
greener alternative binder from Portland cement [1].
Fly ash is the waste residue that results from the
combustion of coal in thermal power station is available at
large scale all over the world. In India more than 100
million tons of fly ash is produced annually. Out of this, only
17 – 20% is utilized either in concrete or in stabilization of
soil. Most of the fly ash is disposed off as a waste material
that coves several hectors of valuable land. As fly ash is light
in weight and easily flies, this creates severe health
problems like asthma, bronchitis, and so forth. There are
environmental benefits in reducing the use of Portland
cement in concrete, and using a by-product material, such
as fly ash as a substitute. With silicon and aluminium as the
main constituents, fly ash has great potential as a cement
replacing material in concrete. For every ton of fly ash used
in place of Portland cement saves about a ton of carbon
dioxide emission to the atmosphere [2].
Davidovits proposed a new term geopolymer in 1978 to
represent the mineral polymers resulting from
geochemistry. Geopolymers are members of the family of
inorganic polymers in which the mineral molecules are
linked with covalent bond. Geopolymers are produced by
source materials or by-product of geological origin that is
rich in silica and alumina like fly-ash when react with
alkaline solution at elevated temperature. The chemical
reaction that takes place in this case is polymerization, so
this binder is called geopolymer. Geopolymer concrete is a
new type of concrete in which cement is fully replaced by
the pozzolanic materials that is rich in Silicon (Si) and
Aluminium (Al) like fly ash. It is activated by highly alkaline
liquids to produce the binder which binds the aggregates in
concrete when subjected to elevated temperature. The