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Copyright: © 2017 De Soyza SG, et al.
Open Access Research Article
Journal of Molecular Nanotechnology and Nanomedicine
J Mol Nanot Nanom
Page 1 of 6
Antimicrobial Potential in Biogenic Silver Nanoparticles Synthesized
from Plectranthus zeylanicus
Sudhara G. De Soyza
1
, W.M.D Gaya Bandara Wijayaratne
2
, Mayuri Napagoda
1
* and Sanjeeva Witharana
3
1
Department of Biochemistry, Faculty of Medicine, University of Ruhuna, Galle 80 000, Sri Lanka
2
Department of Microbiology, Faculty of Medicine, University of Ruhuna, Galle 80 000, Sri Lanka
3
Faculty of Engineering, Higher Colleges of Technology, Ras Al Khaimah, United Arab Emirates
Abstract
Out of all metals, silver has been widely recognized for its
antimicrobial activity over centuries of years. In more recent times,
silver was found to be even more effective in antimicrobial activity
when it was at nanoscale. A novel protocol was developed for green
synthesis of silver nanoparticles and their anti-bacterial activity was
experimentally validated. This protocol is different from the prior
art in a way that the green synthesis from non-polar organic plant
extracts is now possible for the first time. The raw material was the
dichloromethane extract of Plectranthus zeylanicus, a widely used
medicinal plant in Sri Lanka. Scanning electron microscopy (SEM)
images of the formulation revealed that the synthesized objects were
predominantly of spherical shape and approximately 100 nm in size.
Energy dispersive X-ray (EDX) spectrum confirmed the presence of
elemental silver in it. The presence of phytochemical classes that could
be responsible for the green synthesis of nano silver was detected by
standard qualitative phytochemical screening assays. The antibacterial
activity of the compound was assessed by the agar well diffusion
method against Gram positive and Gram negative bacteria including
the methicillin resistant Staphylococcus aureus (MRSA). These new
formulations exhibited profound antibacterial activity against all the
tested microorganisms in comparison to aqueous silver ion solution and
commercial disinfectants that contain silver ions as active ingredients.
This is the first time the anti-MRSA potential of silver nanoparticles
synthesized via a green route is documented. Present findings point
towards the possible application of biogenic silver nanoparticles as an
effective antimicrobial agent against nosocomial infections.
Keywords: Antimicrobial; Nosocomial; Biogenic; Plectranthus
zeylanicus; Green synthesis; Silver nanoparticles
Abbreviations
DCM: Dichloromethane; EDX: Energy-dispersive X-ray; MIC:
Minimum Inhibitory Concentration; MRSA: Methicillin resistant
Staphylococcus aureus; SEM: Scanning Electron Microscopy.
Introduction
The outbreak of new infecting diseases and the evolution
of commensal and pathogenic microorganisms to problematic
strains due to the acquisition of resistance to currently employed
antimicrobial agents have become critical issues especially in
the hospital settings. Acquisition of antimicrobial resistance is
associated with negative outcomes that include increased mortality
and morbidity, increased length of stay in the hospital, and the
requirement of more costly alternative antimicrobial therapy and
infection control interventions [1]. Thus the development of novel
antimicrobial substances with diverse chemical structures and
novel mechanisms of actions has been highly emphasized by the
scientific community.
Metals and metalloids have been widely employed in the field
of medicine for thousands of years owing to their antimicrobial
properties. For example, the empirical usage of silver, copper and
zinc was prevalent until the discovery of antibiotics in the 20
th
century. However, due to the consecutive outbreaks of multidrug-
resistant pathogens and the scarcity of remedial antimicrobials in
the pipeline, a revival of antimicrobial metals is observed in the
recent years [2].
Current developments in the field of nanotechnology have led
to the enhancement of intrinsic antimicrobial activity of the metals,
when they are in the form of nanoparticles. For example Dobrucka
et al. [3] witnessed the ZnO nanoparticles inhibit the growth of
Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa;
Shamaila et al. [4] recorded nano Au activity against E .coli, S. aureus,
Bacillus subtilis and Klebsiella pneumonia; Roy et al. [5] observed nano
CaO active against P. aeruginosa and Staphylococcus epidermidis;
Kasha et al. [6] reported CuO nanoparticles inhibit E. coli, P.
aeruginosa, Proteus vulgaris and S. aureus [6], and Zimbone et al. [7]
noticed the nano TiO
2
activity on E. coli; to name a few. Nonetheless
silver is the more effective antimicrobial agent against bacteria,
viruses and other eukaryotic microorganisms than other metals such
as copper, titanium, magnesium, zinc or gold [8], and therefore the
most widely examined inorganic nanomaterial for an antimicrobial
agent [9–14]. Since the conventional chemical and physical methods
involved in the synthesis of metal nanoparticles are costly and
potentially harmful to the environment, recently, the attention is
paid on the green synthesis of metal nanoparticles as an alternative,
efficient, inexpensive, and environmentally safe approach. It is well
evident that the reductive capacities of the proteins and metabolites
present in plants, algae, bacteria, yeast, fungi etc. could significantly
contribute to the transformation of inorganic metal ions into metal
nanoparticles. Among these organisms, plants seem to be the best
candidate and are suitable for rapid, large scale biosynthesis of
nanoparticles of high stability. It is speculated that the various plant
metabolites, such as terpenoids, polyphenols, sugars, alkaloids,
phenolic acids, and proteins, could play an important role in the
bioreduction of metal ions, yielding nanoparticles [15].
Sri Lanka is a country blessed with a great wealth of medicinal
plants that could harbor diverse chemical components of high
pharmacological potential; nevertheless, a large portion of Sri
Lankan flora remains phytochemically and pharmacologically
unexplored. Thus the present investigation is focused on harnessing
the secondary metabolites in a popular medicinal plant in Sri Lanka,
Plectranthus zeylanicus, for the biosynthesis of silver nanoparticles
and evaluation of possible antimicrobial effects of the prepared
silver nanopreparations. In contrast to the prior studies where the
aqueous or hydro-alcoholic extracts of plants have been utilized
for the green synthesis, the synthetic capacity of the low polar
secondary metabolites in lipophilic plant extracts in the generation
of biogenic nanoparticle was evaluated in this study.
Received Date: April 29, 2017, Accepted Date: June 13, 2017, Published Date: June 20, 2017.
*Corresponding author: Mayuri Napagoda, Department of Biochemistry, Faculty of Medicine, University of Ruhuna, Galle 80 000, Sri Lanka, Tel: +94-071-
921-6281; Fax: +94-912-222-314; E-mail: mayurinapagoda@yahoo.com.