Research Article
Vacuum Ultraviolet Field Emission Lamp
Consisting of Neodymium Ion Doped Lutetium
Fluoride Thin Film as Phosphor
Masahiro Yanagihara,
1
Takayuki Tsuji,
1
Mohd Zamri Yusop,
1,2
Masaki Tanemura,
1
Shingo Ono,
1
Tomohito Nagami,
3
Kentaro Fukuda,
3
Toshihisa Suyama,
3
Yuui Yokota,
4
Takayuki Yanagida,
5
and Akira Yoshikawa
4
1
Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Aichi 466-8555, Japan
2
Department of Materials, Manufacturing & Industrial , Faculty of Mechanical Engineering, Universiti Teknologi Malaysia (UTM),
81310 Skudai, Johor, Malaysia
3
Tokuyama Corporation, Kasumigaseki Common Gate West Tower 2-1, Kasumigaseki 3-chome, Chiyoda-ku, Tokyo 100-8983, Japan
4
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
5
Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu 808-0196, Japan
Correspondence should be addressed to Shingo Ono; ono.shingo@nitech.ac.jp
Received 16 July 2014; Accepted 24 August 2014; Published 11 September 2014
Academic Editor: Xiao-Feng Zhao
Copyright © 2014 Masahiro Yanagihara et al. his is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
A vacuum ultraviolet (VUV) ield emission lamp was developed by using a neodymium ion doped lutetium luoride (Nd
3+
: LuF
3
)
thin ilm as solid-state phosphor and carbon nanoiber ield electron emitters. he thin ilm was synthesized by pulsed laser
deposition and incorporated into the lamp. he cathodoluminescence spectra of the lamp showed multiple emission peaks at 180,
225, and 255 nm. hese emission spectra were in good agreement with the spectra reported for the Nd
3+
: LuF
3
crystal. Moreover,
application of an acceleration voltage efectively increased the emission intensity. hese results contribute to the performance
enhancement of the lamp operating in the VUV region.
1. Introduction
Vacuum ultraviolet (VUV) light has been used in numerous
ields, such as cleaning, surface modiication, and steriliza-
tion, because short wavelength light with high photon energy
is capable of breaking strong chemical bonds [1–3]. herefore,
performance improvements of VUV lamps contribute to the
progress of these applications. he VUV gas lamp has widely
been used [4–6] but presents limited stability, lifetime, and
size. VUV lamps using a solid-state phosphor have attracted
considerable attention as alternate light sources because they
exhibit less deterioration, less luctuation, and higher density
than gas lamps [7, 8]. hese lamps require wide band gap
materials but few solid-state phosphors have substantial band
gaps. Group III nitrides are suitable because they present a
direct transition type band structure with a wide band gap
[9, 10]. However, even when using AlN, which emits light at
a relatively short wavelength, the operating wavelength was
limited to deep UV region [9, 11–13]. he wide band gap
of diamond can be applied to UV but not to VUV lamps
[14]. On the other hand, some luorides have band gaps that
are suiciently wide to enable light emission in the VUV
region [15, 16]. Fluoride composite materials have been widely
studied as laser materials, scintillation materials, and optical
materials because of their extremely wide band gap [17–
24]. Speciically, a KMgF
3
thin ilm acting as a solid-state
phosphor and carbon nanoiber (CNF) ield electron emitter
has previously been incorporated into a VUV lamp [25].
he emission spectra from the lamp showed two emission
peaks at 155 and 180 nm in the 140–200 nm wavelength range,
showing that solid-state phosphors can be exploited in VUV
lamps.
Hindawi Publishing Corporation
e Scientific World Journal
Volume 2014, Article ID 309091, 5 pages
http://dx.doi.org/10.1155/2014/309091