This is a refereed journal and all articles are professionally screened and reviewed ORIGINAL A RTICLE
Advances in Environmental Biology, 3(2): 204-209, 2009
ISSN 1995-0756
© 2009, American-Eurasian Network for Scientific Information
204
Corresponding Author
A.S.Y. Ting, Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Jalan
Genting Kelang, Setapak 53300, Kuala Lumpur, Malaysia.
Phone No. : 603-41079802; Fax No. : 603-41079803
E-mail: adelsuyien@yahoo.com; tingsy@utar.edu.my
Utilization of Non-viable Cells Compared to Viable Cells of Stenotrophomonas
Maltophilia for Copper (Cu(ii)) Removal from Aqueous Solutions
A.S.Y. Ting and C.C. Choong
Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Jalan Genting Kelang, Setapak 53300,
Kuala Lumpur, Malaysia.
A.S.Y. Ting and C.C. Choong.: Utilization of Non-viable Cells Compared to Viable Cells of
Stenotrophomonas Maltophilia for Copper (Cu(ii)) Removal from Aqueous Solutions, Adv. Environ.
Biol., 3(2): 204-209, 2009
ABSTRACT
Stenotrophomonas maltophilia is an important bacterium in heavy metal bioremediation. Their application
is however limited by the increasing reports of their pathogenic potential and resistance to common antibiotics.
Therefore, non-viable cells present an interesting alternative as biosorbents. This study was conducted to
investigate the potential of S. maltophilia in non-viable cell forms to remove copper (Cu(II)) from aqueous
solutions. The total amount of Cu(II) removed by viable cells and adsorped by non-viable cells were compared
and analyzed using equilibrium and kinetic models. Results showed that non-viable cells of S. maltophilia have
higher efficacy in removing Cu(II) via surface sorption with 23.900 mg g Cu(II) adsorped compared to only
-1
10.515 mg g dry biomass of Cu(II) removed by the viable cells. The adsorption mechanisms complied with
-1
the Langmuir equilibrium model (R value of 0.9957) and the pseudo second order kinetic model (R value
2 2
of 1.000). Thus the adsorption was attributed to the functional groups on the cell wall via the monolayer
adsorption capacity. Our study showed that non-viable cells of S. maltophilia can be applied and used more
effectively than viable cell forms to remove Cu(II) from aqueous solutions.
Key words: copper (Cu(II)), heavy metal pollutants, non-viable cells, Stenotrophomonas maltophilia, viable cells
Introduction
Copper (Cu(II)) is one of the six main metal
ions with most immediate concern to the environment
[1]. Copper pollution is ubiquitous in the
environment, caused by the industrial effluents
discharged from metal processing industries [2], from
the electronic industries, and also from wastes
derived from pharmaceutical and agricultural
applications. High Cu(II) concentrations in waste
water can easily seep into our water supply and food
chain [3], causing acute Cu(II) poisoning in living
organisms [4].
Early investigations have suggested that Cu(II)
can be removed from the environment with the use
of microorganisms tolerant to high levels of Cu(II)
[5,6]. However, not all of these isolates can be
readily introduced into the environment for intensive
application as they may have pathogenic potential [7,
8] or are known to show resistance to common
antibiotics [9]. As an alternative, non-viable cells
(dead cells) of the tolerant strains can be studied for
their potential in heavy metal removal, thus enabling
the use of even strains with pathogenic potential.
The removal of heavy metal like Cu(II) in dead
cells is through the biosorption mechanism. The
biosorption process is a passive and a metabolic
independent process [10]. It takes place in the cell
wall and the process is rapid and can remove a high
percentage of cations (heavy metals). The efficacy of