International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 07 | July -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1433
Evaluation of performance of Geopolymer Concrete in acid environment
P Abhilash
1
, C Sashidhar
2
and I V Ramana Reddy
3
1
Research Scholar, Department of Civil Engineering, Jawaharlal Nehru Technological University Anantapur,
Anantapuram, Andhra Pradesh , India, 515002
2
Professor, Department of Civil Engineering, Jawaharlal Nehru Technological University Anantapur, Anantapuram,
Andhra Pradesh , India, 515002
3
Professor, Department of civil engineering, Sri Venkateshwara University, Tirupati, Andhra Pradesh , India, 517502
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ABSTRACT: The degradation of concrete by acid attack has been a major problem which needs to be addressed with the
utmost concern. This acid attack is primarily due to acid rain in low concentrations. This attack depends upon both type of the
acid and the concentration of the acid and the vulnerability of concrete. Portland cement concrete due to high alkanity may be
prone to acid attack by acidic environment. The emergence of new alternative materials needs to address this issue by
resisting acid attack to a large extent. Geopolymer materials are polymer minerals which are based on silica and alumina
compounds. The process of corrosion of geopolymer concrete is tough compared to that of conventional concrete. An
experimental study was conducted to evaluate the resistance of geopolymer concrete and Portland cement concrete to acid
environment. Durability of the concrete specimens were analyzed by immersing them in 2% concentration solutions for a
period of 28, 56 and 112 days, In evaluation of their resistance on basis of change of weight and compressive strength. Results
indicated that Geopolymer concrete was highly resistant to sulphuric acid and hydrochloric acid.
Keywords - Geopolymer Concrete, Sulphuric Acid, hydrochloric acid, Silica, Alumina.
1. INTRODUCTION
Durability of concrete is the most crucial property which
evaluates the life of concrete. Interactions of concrete with
external environment is one of the important factors
which indicates the durability of concrete. Among
environmental factors like thaw, abrasion and corrosion
and acid attack, acid attack is the most threatening
parameter. There are many chemical attacks like acid
attack, alkali attack etc. [1]. The extent of deterioration
during an acid attack on concrete depends on the chemical
nature of anions present. Aggregate type and concrete also
influence the extent and intensiveness of acid attack.
Though ordinary Portland cement (OPC) is the widely used
binder in construction industry, its resistance to chemical
attacks such as acids, chlorides and sulfates is a major
concern. Acid attack has not traditionally attracted much
attention, even when cement composites are severely
damaged by acids wherein calcium hydroxide is dissolved
and the hydrated silicate and aluminium phases are
decomposed. In the past few many years geopolymer
binders have emerged as one of the possible opportunity
to opc binders because of their mentioned excessive early
energy and resistance against acid attack [2] apart from its
environmental friendliness. Fly ash based geopolymers are
one branch in the geopolymer family and these have
attracted more attention since the 1990s. As a novel
binder the overall performance of fly ash based
geopolymers is promising specially in some competitive
situations where portland cement concretes are prone to
acid environment[3]. Geopolymer binders might be a
promising opportunity in the improvement of acid
resistant concrete. Given that geopolymers are a unique
binder that relies on alumina silicate instead of calcium
silicate hydrate bonds for structural integrity they were
reported as being acid resistant. Davidovits et al. [4]
Determined that metakaoline based geopolymer has very
low mass loss while samples have been immersed in 5%
sulphuric acid solutions for four weeks Bakharev T. [5]
Studied the resistance of geopolymer materials organized
from fly ash in opposition to 5% sulfuric acid as much as
five exposure and concluded that geopolymer materials
have better resistance than ordinary cement counterparts.
X.J. Song et al. [6] Performed an accelarated test to
evaluate the durability of geopolymer concrete in a 10%
sulfuric acid answer for 56 days and reported its its good
durability. S.E. Wallah and B.V. Rangan [7] Have shown
that geopolymer composites possesses good durability in
examination carried out to assess the long time properties
of fly ash based geopolymers. Allahverdi Ali and Skavara
[8-9]conducted tests to study the mechanism of corrosion
of geopolymer cements in high and low concentrations of
sulfuric acid. The absence of standard methods to evaluate
the performance of cements in acid environments has led
to research in different exposure conditions and
procedures by various authors making it difficult to