Perovskite oxides applications in high temperature oxygen separation, solid oxide fuel cell and membrane reactor: A review TaggedPD1X X Jaka SunarsoD2X X a, *, D3X X Siti Salwa HashimD4X X a , D5X X Na ZhuD6X X b , D7X X Wei ZhouD8X X c, * TaggedP a Faculty of Engineering, Computing and Science, Swinburne University of Technology, Jalan Simpang Tiga, 93350 Kuching, Sarawak, Malaysia b Xinglin College of Nantong University, No.999 Waihuandong Road, Nantong 226008, PR China c Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, No.5 Xin Mofan Road, Nanjing 210009, PR China TAGGEDPARTICLE INFO Article History: Received 25 August 2016 Accepted 20 March 2017 Available online 4 April 2017 TAGGEDPABSTRACT Perovskite oxides have substantial role in the sustainable energy delivery as reflected by their applicability as oxygen-transporting membranes (OTMs), as electrode/electrolyte components in solid oxide fuel cells (SOFCs), and as OTM-based reactors. These applications represent three major directions that enable the membrane-based oxy-fuel combustion technology, the clean and efficient chemical to electrical energy con- version, and the production of higher value-added chemicals from lower value raw materials. The attrac- tiveness of perovskite oxides arises from the possibility to incorporate different A-site and B-site metal elements into their ABO 3-d lattice to form essentially A 1-x A’ x B 1-y B’ y O 3-d compound which allows tailoring of the oxygen non-stoichiometry (and thus the oxygen ionic conductivity), the oxygen reduction reaction activity, and the electronic conductivity to fit a particular application. This paper reviews the basic aspects and progresses in these three directions. The advantages and limitations of perovskites in each application are highlighted and discussed as well as the pertaining aspects. © 2017 Elsevier Ltd. All rights reserved TaggedPKeywords: Perovskite Oxygen separation membrane Solid oxide fuel cell (SOFC) Membrane reactor Contents 1. Introduction ......................................................................................................................................................... 58 2. Perovskite membranes for oxygen separation................................................................................................................ 59 2.1. Oxygen permeation ........................................................................................................................................ 60 2.2. Progress in perovskite-type oxygen permeation membrane ...................................................................................... 60 2.3. Perovskite membranes integration in oxy-fuel combustion ....................................................................................... 63 3. Perovskites in solid oxide fuel cells ............................................................................................................................. 65 3.1. Perovskites as cathode materials ........................................................................................................................ 65 3.2. Perovskites as electrolyte materials..................................................................................................................... 67 3.3. Perovskites as anode materials .......................................................................................................................... 68 4. Perovskite membrane reactors .................................................................................................................................. 68 4.1. Distributor type perovskite membrane reactors ..................................................................................................... 69 4.1.1. Partial oxidation of methane (POM) .......................................................................................................... 69 4.1.2. Oxidation reforming of methane .............................................................................................................. 70 4.1.3. Oxidation reforming of heptane ............................................................................................................... 70 4.1.4. Oxidative coupling of methane (OCM) ....................................................................................................... 70 4.1.5. Oxidative dehydrogenation of alkane ........................................................................................................ 71 4.1.6. Selective oxidation of ammonia ............................................................................................................... 71 4.2. Extractor type perovskite membrane reactors........................................................................................................ 72 4.2.1. Coupling reactions with water splitting (WS) .............................................................................................. 72 * Corresponding authors. E-mail addresses: jsunarso@swinburne.edu.my, barryjakasunarso@yahoo.com (J. Sunarso), zhouwei1982@njtech.edu.cn (W. Zhou). http://dx.doi.org/10.1016/j.pecs.2017.03.003 0360-1285/© 2017 Elsevier Ltd. All rights reserved. Progress in Energy and Combustion Science 61 (2017) 5777 Contents lists available at ScienceDirect Progress in Energy and Combustion Science journal homepage: www.elsevier.com/locate/pecs