International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1125
Experimental Investigation of Tribological Properties Using
Nanoparticles as Modifiers in Lubricating Oil
Mr. A.B. Najan
1
, Dr. R.R. Navthar
2
, Mr. M.J. Gitay
3
1,2
PG Scholar, Dept. of Mechanical Engineering, DVVP College of Engineering, Ahmednagar, Maharashtra, India
2
Professor, Dept. of Mechanical Engineering, DVVP College of Engineering, Ahmednagar, Maharashtra, India
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Abstract - Nanoparticles can be used as an additive in the
engine oil to improve its tribological properties to reduce wear
and friction of the engine. In this research molybdenum
disulphide (MoS2) and copper oxide (CuO) nanoparticles are
added to engine oil SAE20W50 and tribological properties are
investigated. Samples were prepared of varying percentage of
CuO and MoS2 nanoparticles in engine oil (0.25, 0.5 and 1 wt.
%). The friction and wear tests were performed on DUCOM’s
four ball tribotester and the tests were performed with varying
concentration of nanoparticles in engine oil. Also viscosity
tests were performed on Redwood viscometer for different
samples at three different temperatures. The experimental
observations show that MoS2, CuO nanoparticles added in
engine oil exhibits good friction reduction and anti-wear
properties and also decreased the coefficient of friction as
compared with standard engine oil without MoS2, CuO
nanoparticles. This tribological behavior is closely related to
the deposition of nanoparticles on the rubbing surfaces
Key Words: MoS2, CuO nanoparticles, tribological
properties, engine oil, friction coefficient, wear
1. INTRODUCTION
Nowadays nanoscience is one of the most
expansively developing spheres of world’s science and its
achievements can be applied in different areas of science and
technology. Nanomaterials as an example which are in the
form of so called nanostructures (nanotubes, nanowires,
Nano powders and others) which are widely used in many
human activity fields- from cancer treatment to engineered
textiles or energy storage to rocket explosives and
propellant . In upcoming decades various new fields of
nanostructures application will arise. One of them seems to
be the unexplored area of nanostructures use as additives
modifying properties (especially tribological) of lubricating
or cutting oils.
Nanotechnology is regarded as the most
revolutionary technology of the 21st century. It can be used
in many fields of material science into a new era. In recent
years numerous investigations have been carried out on the
tribological properties of lubricants with different
nanoparticles added in it. A number of papers from different
authors all over the world have concluded that it is
significantly effective to add nanoparticles to lubricant for
reducing wear and friction. Among those that were added
into oils, MoS2 nanoparticles have received much attention
and exhibited excellent applications for their good friction
reduction and wear resistance properties. The interfacial
conditions which affect the reduction of wear are geometry,
normal load, sliding speed, relative surface motion, surface
roughness, vibration and lubrication. In addition, anti- wear
properties, load-carrying capacities and friction reduction
are mainly controlled by the chemical additives in
lubricating fluid under boundary lubrication conditions. As
the addition of a dispersing agent or the use of a surface
modification preparation technique stabilizes the
nanoparticles, inorganic nanoparticles have received
considerable attention in the lubrication field. Nanoparticles
have received considerable attention because of their special
physical and chemical properties. The preparation of
organic–inorganic complex nanoparticles was causing more
interest in science and industry. However, few of them were
used and studied as water base lubrication additives. In
recent years, with the development of nanomaterial, many
scientific researchers added nanoparticles into lubricating
oils to improve extreme pressure, anti-wear, friction
reducing properties, the efficiency and service life of
machinery. The application of advanced nanomaterials has
played an active role in improving and reforming traditional
lubrication technology.
The anti-wear mechanism of nanoparticles when they are
used as additives in lubricants can be explained in three
different ways: nanoparticles may be melted and welded on
the rubbing surface, reacted with the specimen to form a
protective layer, or tribo-sintered on the surface. However,
some authors state that nanoparticles can also act as small
bearings on the rubbing surfaces. Nanoparticles penetrate
into lubricated EHD contacts to form a boundary film via
mechanical entrapment influencing friction and wear. These
nanoparticles are entrained into sliding contacts only when
the film thickness is smaller than the particle size
contributing to the film thickness. The above mentioned
anti-wear mechanisms of the nanoparticles take place only
under mixed and boundary lubrication. Results show that
nanoparticles can improve the tribological properties of the
base oil, displaying good friction and wear reduction
characteristics even at concentrations below 1 wt%.
However, they did not compare the tribological behavior of
coated nanoparticles used as lubricant additives with the
non-coated ones.