International Journal of Physics, 2017, Vol. 5, No. 4, 110-115
Available online at http://pubs.sciepub.com/ijp/5/4/2
©Science and Education Publishing
DOI:10.12691/ijp-5-4-2
Annealing Effect on (SnO
2
)
0.3
:(In
2
O
3
)
0.7
Solar Cell
Prepared by PLD Technique
Abdulmajeed E. Ibrahim
1
, Kadhem A. Aadim
2
, Qutaibah A. Abduljabbar
1,*
1
Department of Physics, University of Tikrit/College of Education
2
Department of Physics, University of Baghdad / College of Sciences
*Corresponding author: qutaibahalrawi5378@gmail.com
Abstract Indium tin oxide (ITO) thin films were produced by Q- switched Nd:YAG laser with wavelength (1064
nm) has 800 mJ peak energy on In
2
O
3
:SnO
2
target with 0.3 ratio on p-type Si and on porous Si to fabricated solar
cell. The as deposited and annealed thin films on glass substrates were characterized by X-ray diffraction Atomic
force microscopy (AFM), UV-visible absorbance and Hall effect measurements. Then the fabricated solar cells
examined in the dark and under illumination for SnO
2
:In
2
O
3
/p-Si and SnO
2
:In
2
O
3
/Psi/p-Si annealed and as deposited
samples.
Keywords: solar cell, pulse laser, porous-Si
Cite This Article: Abdulmajeed E. Ibrahim, Kadhem A. Aadim, and Qutaibah A. Abduljabbar, “Annealing
Effect on (SnO
2
)
0.3
:(In
2
O
3
)
0.7
Solar Cell Prepared by PLD Technique.” International Journal of Physics, vol. 5,
no. 4 (2017): 110-115. doi: 10.12691/ijp-5-4-2.
1. Introduction
Now a day there are many techniques utilized to enhance
solar cell efficiency enhance solar cells efficiency [1].
The generic solar cell is a structure consisting of two
active layers, thin heavily doped top layer called the
emitter or window layer and thick moderately doped
bottom layer, called the base or absorber with opposite
doping [2]. We need to study the optical, structural [3],
morphological [4] and electrical properties for used
material as window in solar cells on the side where light
enters, to reach optimum efficiency [5]
X- ray diffraction used to characterize obtained films
crystallinety. The d
hkl
spacing between crystals planes can
deduced by X-ray diffraction using Bragg's law [6]
hkl
n 2d sin (1)
where Ө is diffraction angle and λ is the used XRD
wavelength.
Scherrer equation formula used to calculate crystalline
size utilize the peaks broadening [7].
0.9λ
G.S
FWHM . cos(θ)
(2)
Where λ is the x-ray wavelength for k
α
transition from Cu
target (1.5406 Å), FWHM is full width at half maximum
and θ is the angle of diffraction.
Several parameters are used to characterize solar cells.
A solar cell under illumination is characterized by
the following parameters: the Short-circuit current, the
open-circuit voltage, the fill factor and the power
conversion efficiency [8]. Fill Factor indicates the quality
of current-voltage characteristics and it depends on the
ability of charges to reach the electrodes which is
governed by recombination processes. The full factor is
directly affected by the values of the cell's series and shunt
resistances [9]. The solar cell efficiency is the ratio for
outcome power to incident light power density [10].
2. Experimental Part
A porous silicon structure is prepared by
electrochemical etching of silicon substrate of (111)
orientation with a resistivity (4 -10) Ω. cm and the etching
cell is made of Teflon. The electrochemical cell used has
two electrode configurations with a platinum electrode as
cathode and silicon wafer as anode. The etching times is
chosen to be 10 min and current (30) mA. The samples are
dipped in (48%) concentration of (HF) acid in mixing
ratio (1 : 1) HF: ethanol with the aid of diode laser source
as an illumination sources. However, the addition of
ethanol to HF eliminates hydrogen and ensures complete
infiltration of HF solution which further improves the
uniform distribution of porosity and thickness.
In
2
O
3
with purity (99.9 %) and SnO
2
powder purity
(99.98 %) by FERAK company, England were mixed with
In
2
O
3
:SnO
2
ratio 30 % in gate mortar to use it to make
pellet target as a disk of 1.5cm diameter using hydraulic
piston under pressure of 6 tons.
SnO
2
: In
2
O
3
thin films were prepared on glass, p-Si and
porous-Si substrates by Q switched pulsed laser (Huafei
Tongda Technology- DIAMOND-288 pattern EPLS) λ =
1064 nm with 800 mJ peak power inside a vacuum chamber
at vacuum (10
-3
Torr) using double stage rotary pump. The
incident beam coming through a window making an angle
of 45° with the target surface. The substrate is placed