International Journal of Greenhouse Gas Control 47 (2016) 137–150
Contents lists available at ScienceDirect
International Journal of Greenhouse Gas Control
j ourna l h o mepage: www.elsevier.com/locate/ijggc
Performance evaluation of PACT Pilot-plant for CO
2
capture from gas
turbines with Exhaust Gas Recycle
M. Akram
a,∗
, U. Ali
a
, T. Best
b
, S. Blakey
a
, K.N. Finney
a
, M. Pourkashanian
a
a
Energy 2050, Energy Engineering Group, Department of Mechanical Engineering, University of Sheffield, Western Bank, Sheffield S10 2TN, UK
b
Faculty of Engineering, University of Leeds, Leeds LS2 9JT, UK
a r t i c l e i n f o
Article history:
Received 17 July 2015
Received in revised form
24 November 2015
Accepted 29 January 2016
Keywords:
Post-combustion CO2 capture
Gas turbines
Exhaust Gas Recycle
Process modelling
Specific reboiler duty
a b s t r a c t
Exhaust Gas Recycle (EGR) is one of the technologies used to increase the CO
2
concentration in the gas
turbine flue gas. This paper presents the results of an experimental campaign carried out at the Pilot-scale
Advanced Capture Technology (PACT) facilities at the UK Carbon Capture and Storage Research Centre
(UKCCSRC). A 100 kW
e
Turbec T100 PH microturbine was integrated with a post combustion CO
2
capture
plant that has a CO
2
capture capacity of one ton per day. The impact of different CO
2
concentrations
(representing a range of EGR ratios) on the post-combustion CO
2
capture process was experimentally
evaluated using 30% (wt.%) Monoethanolamine (MEA) solvent. It was observed that the specific reboiler
duty was reduced by around 7.1% per unit percentage increase in CO
2
concentration. Overall, it was seen
that the higher the CO
2
concentration, the lower the specific reboiler duty at a fixed capture rate. Both
rich and lean solvent loadings increased with increase in flue gas CO
2
concentration. Energy balance on
the stripper has shown that steam generation rate and condenser duty increases with increase in CO
2
concentration. The experimental data was used to develop and validate the model for the Pilot-scale
amine capture plant using Aspen HYSYS.
© 2016 Elsevier Ltd. All rights reserved.
1. Introduction
According to a recent report published by the Energy Tech-
nologies Institute (Day, 2015), deployment of Carbon Capture and
Storage (CCS) will save tens of billions of pounds (up to 1% of the
GDP by 2050) from the annual cost of meeting climate change tar-
gets compared to non CCS technologies. Delays in deploying CCS
would require advancing other ways of cutting emissions, such as
substantial moves away from gas heating in the 2020s, which are
risky and more costly. A complete failure in CCS deployment would
result is doubling the annual cost of carbon abatement. According
to the report, deploying 10 GW of CCS capacity by 2030 will deliver
high value for the UK economy.
In the power sector, gas is still a major player in the UK and
will become more so over the next few decades. According to the
Department of Energy and Climate Change (DECC), in 2010, 40%
of the UK energy was from gas. In the next few years, many of
the existing coal-fired power stations in the UK are expected to
∗
Corresponding author at: Energy 2050, Energy Engineering Group, Department
of Mechanical Engineering, The Arts Tower – First Floor, Western Bank, University
of Sheffield, Sheffield S10 2TN, UK.
E-mail address: m.akram@sheffield.ac.uk (M. Akram).
close and will be replaced primarily by natural gas and renewables
(DECC, 2011). It seems likely that for energy security, ahead of CCS
deployment, a wave of investment is required in unabated gas fired
power plants in early 2020s (Day, 2015). This shift in the fuel mix
of the UK to natural gas means that the de-carbonisation of the
electricity system required to meet the UK’s emissions reduction
targets beyond 2020 cannot be achieved without CO
2
capture and
storage technology deployed to gas fired power stations (Bassi et al.,
2012).
Post combustion CO
2
capture utilising liquid solvents is by far
the most developed and understood process (Thimsen et al., 2014)
as it has been applied in urea manufacturing and gas sweetening
process for decades. However, its application to the power sector is
relatively new. Though feasible, the process poses many challenges
due to the presence of impurities in the power plant flue gases.
However, the most significant challenge is the energy penalty
caused by the capture process which will increase electricity
production costs. The problem is more significant in the case of gas
fired power plants due to low partial pressure of CO
2
in the flue
gas produced by gas turbines. The CO
2
concentration is limited
by metallurgical constraints due to which gas turbine combustion
systems are very lean. The cost of CO
2
capture from gas fired power
plants can be reduced by enhancing the concentration of CO
2
in the
exhaust gas. One of the technologies to increase the concentration
http://dx.doi.org/10.1016/j.ijggc.2016.01.047
1750-5836/© 2016 Elsevier Ltd. All rights reserved.