Poll Res. 36 (3) : 428-436 (2017)
Copyright © EM International
ISSN 0257–8050
*Corresponding author’s email : Hamed.biglari@gmail.com
ANILINE ADSORPTION FROM AQUEOUS SOLUTIONS USING
DRIED ACTIVATED SLUDGE
MOHAMMAD MOBINI
1
, HAMED BIGLARI
2,*
, ABDOLAH DARGAHI
3
, AMIN ZAREI
4
,
MOHAMMAD REZA NAROOIE
5
, EHSAN ABOUEE MEHRIZI
6
AND
MOHAMMAD MEHDI BANESHI
7
1
Department of Environmental Health Engineering, School of Health, Rafsanjan University of Medical Sciences,
Rafsanjan, Iran.
2
Department of Environmental Health Engineering, School of Public Health, Gonabad University of Medical
Sciences, Gonabad, Iran.
3
Research Center for Environmental Determinants of Health (RCEDH), Kermanshah University of Medical
Sciences, Kermanshah, Iran.
4
Department of Environmental Health Engineering, School of Health, Torbat Heydariyeh University of Medical
Sciences, Torbat Heydariyeh, Iran.
5
Department of Environmental Health Engineering, School of Public Health, Iranshahr University of Medical
Sciences, Iranshahr, Iran.
6
Department of Environmental Health Engineering, Faculty of Public Health, North Khorasan University of
Medical sciences, Bojnurd, Iran.
7
Social Determinants of Health Research Center, Yasuj University of Medical Sciences, Yasuj, Iran.
(Received 1 February, 2017; accepted 30 July, 2017)
ABSTRACT
Aniline is a simple cyclic aromatic compounds and tough biodegradable as well as it is one the
most widely used materials in various industries. This super-toxic substrate due to its high
solubility can be found in abundance in surface and underground waters and has harmful effects
on human health and the aquatic animals. The aim of the present study was to remove the aniline
using dried activated sludge (DAS). In this experimental research, the effect of influencing
variables such as pH (3, 5, 7, 9 and 11), contact time (15 to 120 min), adsorbent dose (0.2, 0.4, 0.6, 0.8
and 1.5 mg/l) and aniline initial concentration (10- 250 mg) were examined. Adsorption isotherms
were assessed using Freundlich, Langmuir and Temkin isotherms, and uptake kinetic was
evaluated by pseudo-first and second order kinetics. The results of the present study indicated that
the maximum efficiency of dried activated sludge in the removal of aniline was equal to 75.12% and
optimum conditions involving pH of 11, 30 min contact time, adsorbent dose of 0.6 mg/l and initial
concentration of 100 mg/l. In addition, check out the adsorption isotherm demonstrated that the
data were better matched with Langmuir adsorption model (R2 0.968) and was followed pseudo-
first order kinetic model.
KEY WORDS: Aniline, Bio-adsorption, Aqueous Solutions, Dried Activated Sludge
INTRODUCTION
One of the most common problems in majority of
industries is high volume of wastewater disposal
with high potential of toxic organic substances;
annually thousands of compositions of these
materials (Bazrafshan et al., 2012b, Alipour et al.,
2017, Sohrabi et al., 2016), as toxic volatile organic
compounds (VOCs) can be found in wastewater
treatment and collection system (Biglari et al., 2016b,
Biglari et al., 2016d; Sohrabi et al., 2017b). Therefore,
how to remove these contaminants is of
considerable importance (Mostafapour, 2011,
Ahamadabadi et al., 2016). Aniline, C6H5NH2, is a