International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 4098
A Review on Aerogel An Introduction
Ghodake Sagar S.
1
, Londhe Babasaheb C.
2
1
Department of Mechanical Engineering,S.N.D.COE &RC,Maharastra,India
2
Asso.Prof.,Department of Mechanical Engineering,S.N.D.COE &RC,Maharastra,India
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Abstract – Aerogel is a solid with extremely low density and
low thermal conductivity. Nicknames include frozen smoke,
solid smoke, solid air, or blue smoke owing to its translucent
nature and the way light scatters in the material. It look like
expanded polystyrene to the touch. It can be made from a
variety of chemical compounds. by extracting the liquid
component of a gel through supercritical drying Aerogel is
produced. This liquid can be slowly dried off without changing
the solid matrix in the gel, as would happen with conventional
evaporation. The first aerogels were produced from silica gels..
Aerogel does not have a designated material with set chemical
formula but the term is used to group all the material with a
certain geometric structure. Aerogel has become a material of
interest to scientists in recent decades due to its unique
physical properties that give it the potential to improve
technologies in a variety of fields. In particular, aerogels offer
the lowest densities and the lowest thermal conductivities of
any known solid. Since then, many other types of aerogels have
been created, including carbon-based and clay-based aerogels.
Silica-based aerogels are the simplest and most widely studied
type of aerogel, with new uses and applications arising ever.
The goal was to create a reliable, non-toxic method, using
inexpensive materials
Key Words: Aerogel, Material, silylating agents, Airglass,
Alcogel
1.INTRODUCTION
)n ͳͻ͵ͳ, ǮSteven Kistlerǯ made a bet with a colleague that he
could prove a wet gel contained a solid matrix the same size
and shape of the gel. To do this he began with a gel and
extracted the liquid, leaving a low-density solid behind.
Using an autoclave to drive the liquid past its critical point he
was able to conquer the obstacle of surface tension which
would otherwise rip apart the internal solid structure of the
gel. His successful wager produced the first silica-based
aerogel. For half a century this curious material went
relatively unnoticed, due to the notorious difficulties and
safety issues involved in its creation .
In the early years, fabricating aerogels meant sending
alcohol to volatile pressures and temperatures in order for it
to reach its supercritical point and allow for the
supercritical-extraction of the gel. Then, in the ͳͻͺͲǯs,
interest was renewed when a French scientist, attempting to
improve the fabrication process for the French government,
developed a process which used less-toxic materials. He
switched out methyl alcohol and Tetra Methyl Ortho Silicate
(TMOS) for the safer pairing of ethyl alcohol and Tetra Ethyl
Ortho Silicate (TEOS). The next breakthrough came in the
early ͳͻͻͲǯs when liquid carbon dioxide replaced the ethyl
alcohol involved in the gel before the sample was taken
through the supercritical process. This allowed scientists to
bypass the dangerous pressures and temperatures needed to
send the pure ethanol past its supercritical point. Liquid
carbon dioxide has the relatively mundane requirements of
305 K and 1050 psi to be brought to its supercritical point.
To obtain hydrophobic low density and low thermal
conductivity aerogels for thermal insulation and liquid
marble formation purpose, various sol-gel parameters,
processing parameters namely washing, shaking, various
solvents, silylating agents and drying method were varied
along with doping the gel with TiO2 powder.
Aerogel is a typical nano-porous thermal insulation material
with open-cell structure. Due to the excellent properties,
aerogel is widely applicable in industry fields such as
astronautics, thermal insulation and so on. However, the
extremely low porosity and complicated structure make it a
challenge to accurately predict the effective thermal
conductivity and enhance the insulation performance. The
experimental measurements of the aerogel thermal
conductivity under different pressure and temperature. Most
of the present researches adopted some regular structure to
represent the aerogel structure, which can simplify the heat
transfer analysis of materials, but also contain artificial
parameters and ignore the stochastic characteristic of
aerogel material. In the aspect of numerical study, used the
macroscopic numerical method to obtain the thermal
conductivity, whereas using traditional numerical methods
is hard to solve the micro-scale heat transfer problem. the
open-cell micro-porous random structure of aerogel was
reconstructed basing on the solid-phase growth principle,
which has no artificial parameters and guarantees the
stochastic characteristic of aerogel material. Then the lattice
Boltzmann method was adopted to predict the aerogel
effective thermal conductivity.
The increase of building energy consumptions driven by the
higher expectations for indoor comfort, together with
concerns for the rise in GHG emissions, are pushing the
research and design interest toward energy saving in
buildings. The development of new insulating materials is
among the most promising options. The aerogels are
considered one of the most promising family of materials for
insulating purposes, given their high thermal insulation.
They are dried gels with such a high porosity that they have
lower thermal conductivity than air. Moreover, they are