IJSRST1731028 | 02 Nov 2017 | Accepted: 30 Dec 2017 | November-December - 2017 [(3) 8 : 1388-1392]
© 2017 IJSRST | Volume 3 | Issue 8 | Print ISSN: 2395-6011 | Online ISSN: 2395-602X
1388
Green Synthesis of CuO Nanoparticles using Ziziphus Mauritiana L. Extract
and Its Characterizations
Shreyas Pansambal
1
, Sonali Gavande
1
, Suresh Ghotekar
2
, Rajeshwari Oza
1
, Keshav Deshmukh*
1
1
Department of Chemistry, S.N. Arts, D.J.M. Commerce and B.N.S. Science College, Sangamner, Savitribai Phule Pune University,
Maharashtra, India
2
Department of Applied Science & Humanities, G. M. Vedak Institute of Technology, Tala, University of Mumbai, Maharashtra, India
ABSTRACT
Copper oxide nanoparticles (CuONPs) synthesized by a completely environmentally safe and facile process using
Ziziphus mauritiana L. aqueous plant extract as an effective stabilizing agent. Phytochemical screening of the fresh
aqueous leaves extract showed the presence of coumarins, tannins, saponins, flavonoids, and glycosides. The
synthesized CuO nanomaterial was characterized by XRD, SEM, EDX, TEM and surface area. This green synthesis
route indicates that, it is efficient method than chemical method.
Keywords: Nanotechnology, Ziziphus mauritiana L., CuONPs, Phytochemical screening.
I. INTRODUCTION
Nowadays CuONPs have generated a great deal of
interest, especially in the field of gas sensing [1],
catalysis [2] and biomedical [3] because of their
remarkable applications. These CuONPs fabricated
using different synthetic routes such as ionic liquid
assisted, microwave irradiation, sonochemical,
electrochemical, sol-gel technique and thermal treatment
[4-9] have been reported. Nevertheless, these routes
have some drawbacks like the use of toxic chemical, use
of acrimonious synthesis conditions like high
temperature and requirement of external additives during
the reaction time. Hence there is limited scope for the
development of efficient, environmentally safe and
additive free synthesis of CuONPs. Currently plant
extract mediated nonmaterial synthesis is getting lot of
attention with several advantages offered by chemical
methods [10-12]. The scrutiny of the literature revealed
some notable plant extract used for facile synthesis of
CuO-NPs. For example, Rauvolfia serpentina [13],
Leucaena leucocephala [14], Calotropis gigantean [15],
Aloe barbadensis [16], Ficus religiosa [17], Albizia
lebbeck [18] and Acanthospermum hispidum [19] have
been reported.
Ziziphus mauritiana L. (Figure 1) belongs to family
Rhamnaceae is an annual plant which grows in tropical
and sub-tropical regions of world. Different parts of this
plant have been used in the traditional medicine for the
treatment of different ailments. In this study, we report
the use of Ziziphus mauritiana L. as stabilizing and
reducing agent in the ecofriendly synthesis of CuONPs.
Figure 1. Leaves of Ziziphus mauritiana L.
II. MATERIALS AND METHODS
2. 1. Materials
Copper acetate monohydrate was used as a precursor.
The fresh leaves of Ziziphus mauritiana L. were sourced
from Sangamner college campus, Maharashtra, India.
The collected leaves were washed with deionized water,
cut into small pieces. All glassware’s are washed with
distilled water and acetone and dried in oven before use.