International Journal for Research in Technological Studies| Vol. 4, Issue 8, July 2017 | ISSN (online): 2348-1439
Copyright© IJRTS | www.ijrts.com 34
Abstract— The dairy industry is generally considered to be
one of the largest food processing wastewater in many
countries, especially in India. In dairy industry, in most
cases, the wastewater generated is directly discharged into
the nearby water bodies. Since the dairy waste water
contains large concentration of COD, BOD, and oil, fats,
chloride, and other elements along with several bacteria
these may cause substantial health risk, and serious
environmental issues.. In this paper EC and EDI techniques
are used for the treatment of dairy waste water. The result
shows that Copper electrodes has achieved a maximum
turbidity reduction of 99.5%, COD reduction of 97.5% and
BOD reduction of 90.94% in 30volt high stirring speed
when the electrolysis time is set at 30 mins in
electrocoagulation process. And copper electrodes yielded
97.5%, 84.84% and 99.5% removal efficiency in COD, BOD
and turbidity respectively, under 30volt and 30 min
electrolysis time in electrodeionization process. Both EC
and EDI have achieved COD and turbidity removal up to
95-99% at high voltage and electrolysis time.
Keywords— Electrocoagulation, Electrodeionization, Dairy
Waste Water, Copper Electrodes
I. INTRODUCTION
The dairy industry is generally considered to be one of the
largest food processing industry in many countries. As the
importance of improved standards of wastewater treatment
grows, process requirements have become more advanced
[1]. The type of product being produced, the production
methods, operating methods, design of the processing plant,
the degree of water quality management being applied, and
more, the quantity of water being conserved determines the
concentration, volume, and composition of the effluents
arise from this dairy industry. Due to the presence of organic
load like carbohydrates, proteins and fats originating from
the milk or dairy industry, effluents are concentrated in
nature. However, the dairy wastewaters are characterized by
high biological oxygen demand (BOD) and chemical
oxygen demand (COD) concentrations, high levels of
dissolved or suspended solids including fats, oils and grease,
nutrients such as ammonia or minerals and phosphates and
therefore it requires proper attention before they are
disposed [2]. Due to the presence of organic load due to
carbohydrates, proteins and fats originating from the milk,
dairy industry waste effluents are concentrated in nature [3].
Since these dairy waste streams contain high concentrations
of organic matter, these effluents may cause serious
environmental issues. Introduction of Most of the
wastewater volume generated in the dairy industry results
from cleaning of transport lines and equipment between
production cycles, cleaning of tank trucks, washing of milk
silos and equipment malfunctions or operational errors [4-
7].
Treating dairy wastewater is thus of great
importance not only for the environment, but also for the
purpose of using the recycled water for use in other
industrial processes [8]. Nowadays, there are many
physicochemical and biological methods are used for
treating dairy effluents, with the aim of reducing the volume
of the sludge produced. The physicochemical processes
suffer lots of disadvantage such as reagent costs are high
and the soluble COD removal is low [9]. Moreover, the
chemical treatments can also induce a secondary pollution
due to the fact that chemical additives used for treatment
may contaminate the treated water. Moreover, high removal
rates of the COD are obtained even though this process does
not eliminate the phosphorus and nitrogen compounds
present in the dairy effluents [10]. Implementation of
another complementary physicochemical treatment would
reduce phosphorus and nitrogen content.
In the field of electric field a number of
technologies are developing for treating wastewater.
Electrocoagulation and electrodeionization process are two
among them. Electro coagulation is an electrolytic process
that has been already experienced for the treatment of
various liquid wastes [11]. Electrodeionization (EDI) is a
process by which an electric field is used to remove ions and
polar species from an aqueous stream by combined reverse
osmosis and ion exchange method [12].
Electrocoagulation is the process of destabilizing
suspended, emulsified, or dissolved contaminants in an
aqueous medium by introducing an electrical current into
the medium in an electrochemical cell, usually with an Al or
Fe anode. Electrocoagulation involves the generation of
coagulants in situ by dissolving electrically either aluminum
or iron ions from aluminum or iron electrodes, respectively.
The metal ions generation takes place at the anode, and
hydrogen gas is released from the cathode. The hydrogen
gas would also help to float the flocculated particles out of
the water [13]. In its simplest form, an electrocoagulation
reactor consists of an electrolytic cell with one anode and
one cathode. When these electrodes connected to an external
power source, the anode material will
electrochemically corrode due to oxidation, while the
cathode will undergo passivation [14].
During electrolysis, the positive side of EC cell
undergoes anodic reactions, while on the negative side,
cathodic reactions are undergone. Consumable metal plates,
like iron or aluminum, are usually used as sacrificial
electrodes so as to continuously produce ions in the water.
The released ions neutralize the charged particles and
thereby initiate coagulation. The released ions remove
undesirable contaminants either by chemical reaction and
Electrocoagulation and Electrodeionization Process for Dairy
Wastewater Treatment using Copper Electrode
Gopika G. L
1
Dr. K. Mophin Kani
2
1
PG Student
2
Assistant Professor
1,2
Department of Civil Engineering
1,2
APJ Abdul Kalam Technological University, UKF College of Engineering & Technology,
Kollam, Kerala India