IJSRSET1849130 | Received : 10 August 2018 | Accepted : 25 August 2018 | July-August-2018 [ 4 (9) : 525-533 ]
© 2018 IJSRSET | Volume 4 | Issue 9 | Print ISSN: 2395-1990 | Online ISSN : 2394-4099
Themed Section : Engineering and Technology
525
Treatment of Polluted Aqueous Solutions with different types of
Dyes by Eggplant Peels Accessing to Zero Residue Levels
Mohammed Nsaif Abbas
1
, Firas Saeed Abbas
1*
, Thekra Atta Ibrahim
2
1*
Environmental Engineering Department, Mustansiriyah University, College of Engineering, Baghdad, Iraq
2
Department of Biology, Diyala University, College of Education for Pure Science, Diyala, Iraq
ABSTRACT
This paper is related to study the potential of eggplant peel (EP) to remove nine types of dyes (which were acid
orange, brilliant green, Congo red, crystal violent, direct black, direct brown, indigo carmine, methylene blue,
and yellow dye) from simulated synthetic aqueous solutions (SSAS) using immobilized Polyphenol Oxidase
(PPO) enzyme extracted from EP and adsorption process. Results show high ability of PPO to remove dyes
with an efficiency reach to 99%. The residue from PPO extraction from EP was investigated to remove the
same dyes as adsorbent media. Higher removal efficiency were (93.15, 95.25, 92.55, 94.75, 92.85, 94.65, 90.25,
91.35 and 93.40)% for acid orange, brilliant green, Congo red, crystal violent, direct black, direct brown, indigo
carmine, methylene blue, and yellow dye respectively.
Keywords : Eggplant Peel, Dyes, PPO, Adsorption, Residue and ZRL
I. INTRODUCTION
Several metiers predominantly employ dyes and
tinctures to tint their manufactures, like food, textile
and lather industries, biological research, paper
production, photochemical cell, hair colourings, etc.
[1]. Most dyes are apparent in aqueous systems at very
minimum concentrations nearly (1 mg.l-1). Between
(10-200 mg.l-1) is the range of the concentration of
dyes in the wastewaters produced from textile
industries. Defilement due to the use of dyes may
compose a serious risk because of the enormous
amount release. The discharge of the wastewaters of
dyes to the open waters may present hazardous
problems. In addition to the undesirable aesthetic
problems to the water user, the International Agency
for Research on Cancer (IARC) has categorized many
kinds of dyes like benzidine as being related with the
cancer in humans [2]. The treatment of wastewaters
effluents produced from textile industries using
classical chemical, physical and biological methods
are very difficult issue. Adsorption technology may be
an effective method for treating different types of
water pollutants like odours, suspended solids, oil,
and organic matter [3]. The most widely adsorbent
used in adsorption method was activated carbon due
to its ability to adsorb many metallic ions and organic
matters, but it’s used is decreased now day because
the expensive cost required. So, cheaper materials
instead of activated carbon must be found [4]. Many
substitutes like rice husk, sugarcane bagasse, fly ash,
sludge ash, bituminous coal, maize cob, coconut shell,
wheat straw, cotton waste, groundnut shell, and
orange peel have been proposed as an adsorbent for
various types of dyes [5-14]. The aim of this
investigation is to test the ability of using Eggplant
Peel wastes in two ways for adsorption removal of
various dyes which are acid orange, brilliant green,
Congo red, crystal violent, direct black, direct brown,
indigo carmine, methylene blue, and yellow dye from