Populus Tree Wood: A Noble Bioresource from Western Himalayas for
the Development of Various Carbon Types for the Effective Application in
Environment Protection i.e., Phenol Adsorption from Wastewater
Kumar RD, Kannan GK and Kadirvelu K
*
Bharathiar University, Coimbatore, Tamil Nadu, India
*
Corresponding author: Kadirvelu K, Bharathiar University, Coimbatore, Tamil Nadu, India, Tel: 0422-2428156; E-mail: kadirvelukrishna@yahoo.com
Rec date: September 22, 2017; Acc date: October 26, 2017; Pub date: October 30, 2017
Copyright: © 2017 Kadirvelu K, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium, provided the original author and source are credited.
Abstract
Populus tree is one of the extensively available Bioresource in the foothills of Western Himalayas. Apart from its
multifarious utilities, the activated carbon from the poplar wood has also been finding its enormous use in combating
environmental contaminants. Waste aqueous effluents containing various hazardous chemicals, heavy metals and
dyes etc. cause serious environmental problems which ultimately affect both flora and fauna adversely. Activated
carbon (AC) is being widely used adsorbent for the removal of organic pollutants. The poplar wood carbon (PWC)
when chemically activated with NaOH, HCl, HNO
3
, H
3
PO
4
, H
2
SO
4
, CH
3
COOH and ZnCl
2
caused significant
increase in surface area and pore size development. All the chemically activated carbons (CACs) were subjected to
extensive physiochemical studies like SEM, XRD, FTIR, EDAX and surface area etc. Among all the carbons, the
SEM and surface area analysis of H
2
SO
4
activated carbon showed the maximum pore size of 7.1 µm and leading
surface area of 1045 m
2
/g. These carbons are acidic with their pH
zpc
in the range of 3.6 to 4.1. The carbon is
amorphous in nature as it is showing three typical broad peaks around 26.5, 44.4 and 80° in all the samples. Among
the bulk density of these carbons, ZnCl
2
and H
2
SO
4
activated carbons have maximum of 428 and 427 kg/m
3
respectively. The utilization of these carbons in environmental protection has been studied by carrying out
adsorption studies for the removal of phenol. Direct proportion of phenol adsorption to the adsorbent concentration
was well established. Effect of contact time on adsorption of phenol using 0.5 gm of adsorbent with 25 ml of 1000
ppm adsorbate showed 100% removal of phenol and the equilibrium was attained in almost an hour. Preliminary
studies using poplar wood carbon for the elimination of highly hazardous contaminants has been carried out and the
results have been very encouraging.
Keywords: Bioresource; Poplar wood carbon; Activated carbon;
Chemically activated carbon (CAC); Environment protection
Introduction
India has been fascinating the entire world especially the scientifc
community due to her lush green and diverse fora. Himachal Pradesh
a western Himalayan state of India, is one of the mega biodiversity
centers of the world with all kinds of plants ranging from herbs to
colossal trees. Te altitude of this hilly state ranges from 350 meters to
6975 meters above mean sea level which make it the home for all kind
of fora and fauna. Due to its mountainous geography, a variety of
broad leafed species constitutes its forest. Te Poplar is one such tree
which fnds its agricultural estate in abundance in Himachal. Te tree
is used not only as fodder, fuel and furniture etc., but has also been
widely cultivated to combat soil erosion, deforestation and other
environmental hazards. Te global reported area of planted poplar was
6.7 million ha, of which 3.8 million ha (56%) were planted primarily
for wood production and 2.9 million ha for environmental purposes
[1]. Poplar agro forestry can now be found in many states in India.
Tese include Uttar Pradesh, Punjab, Haryana, Jammu and Kashmir,
Himachal Pradesh and Arunachal Pradesh [2]. Due to rapid Industrial
growth and technological developments across the globe, there is
nonstop quality degradation of both air and water. Along with it, even
constant use of agricultural insecticides, pesticides and heavy metals is
also proving to be a major contributor towards water pollution.
Tese pollutants along with Industrial efuents are persistently
posing threat to whole biodiversity on the planet earth. As the problem
is infuriating day by day, various techniques and technologies are being
developed to combat the problem.
Among various techniques, adsorption is a very popular and widely
used technique. Tis is due to its cost-efectiveness that this technique
is fnding its vast application in controlling the environmental hazards.
Activated carbon is a tasteless, solid, microcrystalline, non-graphitic
form of a black carbonaceous material with a porous structure [3-4].
Activated carbon has been regarded as only one of its kind, fexible and
versatile adsorbent due to its salient and unique characteristics like
large surface area, micro porous structure, high adsorption capacity
and degree of reactivity [5-7]. Tere are many agricultural by- products
which are considered as waste matter. Tese agricultural waste
materials pose numerous disposal problems. But, an economic and
green technology latent in these waste materials has been brought to
the fore by the scientifc world and this material is no more a waste
material but is an eco-friendly as well as economic resource in
controlling environmental pollutants. Tis requires only
transformation of this agricultural waste material into activated
carbon. Such agricultural waste material can be obtained from
diferent agricultural and horticultural crops. For example, activated
carbon can be obtained from various raw materials like Eucalyptus
wood [8], bamboo [9], wood fberboard waste [10], sugar cane bagasse
[11], cotton stalks [12], Casuarina [13] and Pine tree [14] etc.
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ISSN: 2155-6199
Journal of Bioremediation &
Biodegradation
Kumar et al., J Bioremediat Biodegrad 2017, 8:6
DOI: 10.4172/2155-6199.1000415
Research Article Open Access
J Bioremediat Biodegrad, an open access journal
ISSN: 2155-6199
Volume 8 • Issue 6 • 1000415