International Conference on “Applied Nanotechnology and Nanoscience”(ICANN 2017)
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Int. Res. J. of Science & Engineering, 2017; Special Issue A1 : 163-166 SJIF Impact Factor 4.11
ISSN: 2322-0015 UGC Approved Journal No. 63628
RESEARCH ARTICLE OPEN ACCESS
Triton B mediated green protocol for epoxide cleavage
Zade RN
1
, Mude KM
2
, Mude BM
3
, More PS
4
and Patange AN
5
1
Department of Chemistry, Siddharth College, Fort, Mumbai- 400001, India,
2
Department of Physics, Bhavan’s College, Andheri (W) -400058, India,
3
Department of Physics, Ramnarain Ruia College, Matunga (E) -400019, India,
4
Department of Physics, Mithibai College, Vile Parle (W), Mumbai- 400056, India,
5
Department of Chemistry, Bhavan’s College, Andheri (W) -400058, India
Corresponding author email: rzade07@yahoo.co.in
Manuscript Details ABSTRACT
Available online on http://www.irjse.in
ISSN: 2322-0015
Editor: Dr. Arvind Chavhan
Cite this article as:
Zade RN, Mude KM, Mude BM, More PS and
Patange AN. Triton B mediated green protocol
for epoxide cleavage, Int. Res. Journal of Science &
Engineering, December 2017; Special Issue A1 :
163-166.
© The Author(s). 2017 Open Access
This article is distributed under the terms
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made.
Ionic liquids are liquids at room temperature (RTIL) and
have high thermal stability, low vapour pressure,
immiscibility with organic products, high kinetic control.
They are used for synthesis, catalysis and extraction.
Present study encompasses use of Triton B (IL) for
epoxide cleavage to produce various alcohols.
Characterization of product was done using H-NMR, C-
NMR and GCMS. So, this route provides simple,
efficient, environmentally benign way of preparing 1, 2 -
methoxy alcohol from epoxide. After carrying out many
reactions using Triton B as catalyst and reaction medium,
it can concluded that this ionic liquid is recyclable,
reusable reaction medium and catalyst for C-O, C-C
bond formation and epoxide cleavage.
Keywords: Ionic Liquid, epoxide, Triton B.
INTRODUCTION
Organic synthesis has it’s place in classical and applied
research, it is constantly encountered with certain
problems of separation of materials other than products,
huge solvent usage, protection and deprotection of
functional groups, low absolute yield etc. These
limitations are grave in synthesis of fine and specialty
chemicals. [1-2] So there is a growing need for more
environmentally acceptable processes in the chemical
industry. This trend has become known as ‘Green
Chemistry’.