141 Int J Petrochem Res.
ISSN: 2638-1974
Volume 2 • Issue 1 • 1000124
International
Journal of Petrochemistry and Research
Research Article Open Access
Effects of lean alkanolamine temperature on the
performance of CO
2
absorption processes using
alkanolamine solutions
Abolghasem Kazemi*
Chemical engineering department, Isfahan University of Technology, Isfahan, Iran
Article Info
*Corresponding author:
Abolghasem Kazemi
Chemical engineering department
Isfahan University of Technology
Isfahan, Iran
Tel: +989171492783
E-mail: abolghasemkazemi@gmail.com
Received: May 26, 2018
Accepted: May 30, 2018
Published: June 4, 2018
Citation: Kazemi A. Effects of lean alkanolamine
temperature on the performance of CO
2
absorption processes using alkanolamine
solutions. Int J Petrochem Res. 2018; 2(1):
141-147.
doi: 10.18689/ijpr-1000124
Copyright: © 2018 The Author(s). This
work is licensed under a Creative Commons
Attribution 4.0 International License, which
permits unrestricted use, distribution, and
reproduction in any medium, provided the
original work is properly cited.
Published by Madridge Publishers
Abstract
Acid gas removal from the natural gas using alkanolamine processes is the most
common technology used for sweetening of natural gas. Based on the sour and sweet gas
specifications, several alkanolamine solutions can be used for acid gas removal, all of which
are well developed processes. However, one of the remaining issues is the costs associated
with the processes. In this study, DEA, DGA and mixed (MDEA+DEA) processes are designed
for sweetening the natural gas produced in one of the gas fields having high CO
2
/H
2
S ratio.
For each process, seven scenarios are designed to investigate the effects of the cooler’s
operating parameters on the performance of the process. For each scenario, the duty of the
cooler is varied in order to have a specific lean amine temperature entering the absorber.
Each scenario is simulated using Aspen HYSYS and economically evaluated using Aspen
economic evaluation. Based on the results of this study, the required solution circulation
rates slightly increases when the lean amine temperature increases. However, Lower
process capital costs and lower cooler’s duty were obtained by operating the DEA and DGA
processes at higher values of lean amine temperature. Also, operating at lower lean amine
temperatures resulted in lower hydrocarbon pick up in case of MDEA+DEA process.
Keywords: CO
2
; Natural Gas Sweetening; Cooler’s Parameters; DEA; DGA; Mixed Amine
Introduction
The processes using Alkanolamine solutions for acid gas removal from natural gas are
the most common processes used for the removal of acid gases from natural gas. The
alkanolamine processes are well developed processes, each of which is suitable for
sweetening the natural gas with certain sour and sweet gas specifications [1-9]. However,
one of the main issues is the large costs associated with these processes [10-12]. Numerous
studies have been carried out to reduce the costs associated with these processes.
Polasek et al studied alternative flow schemes for natural gas sweetening [11], Bae et
al studied split flow configuration for the process [13], Warudkar et al studied the effects
of stripper operating parameters [10], Cousins et al studied modifications on the process
flow sheet [14], Sohbi et al and Fouad et al studied effects of using mixed alakanolamines
[6, 7], Kazemi et al and Ghanbarabadi et al performed comparative studies between
different processes [15, 16], Nuchitprasitichai et al, Øi et aland Mores et al used optimization
techniques [12, 17, 18] Freeman et al proposed using concentrated piperazine mixtures [8]
and Banat et al used energy analysis method [19] for reducing costs and energy
requirements of the sweetening processes.
For the sweetening of the natural gas with certain specifications, several processes
might be applicable. One of the questions which arise in these situations is that which
process is the most economical process to be used for sweetening of the natural gas with
ISSN: 2638-1974