186 Int J Petrochem Res.
ISSN: 2638-1974
Volume 2 • Issue 2 • 1000133
International
Journal of Petrochemistry and Research
Research Article Open Access
Optimization of preparation conditions for rice husk based
activated carbons for the removal of methylene blue dye
Murat MN
1
, Mohd Azmier Ahmad
1,3
* and Mohd Nazri Idris
2
1
School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
2
Solid Waste Management Cluster, Science & Engineering Research Centre, Engineering Campus, Universiti Sains Malaysia, Nibong
Tebal, Penang, Malaysia
3
School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang,
Malaysia
Article Info
*Corresponding author:
Mohd Azmier Ahmad
School of Chemical Engineering
Engineering Campus, Universiti Sains
Malaysia
14300 Nibong Tebal
Penang, Malaysia
Tel: +604 5996459
Fax: +604 5996908
E-mail: chazmier@usm.my
Received: July 25, 2018
Accepted: August 25, 2018
Published: August 31, 2018
Citation: Murat MN, Ahmad MA, Idris MN.
Optimization of preparation conditions for
rice husk based activatedcarbons for the
removal of methylene blue dye. Int J
Petrochem Res. 2018; 2(2): 186-188.
doi: 10.18689/ijpr-1000133
Copyright: © 2018 The Author(s). This
work is licensed under a Creative Commons
Attribution 4.0 International License, which
permits unrestricted use, distribution, and
reproduction in any medium, provided the
original work is properly cited.
Published by Madridge Publishers
Abstract
This study investigates the optimal conditions for preparation of rice husk based
activated carbon (RHAC) using carbon dioxide gasification of rice husk char undermicrowave
irradiation.The central composite design (CCD) was used todetermine the effects of the two
preparation variables; microwave power and activation time on MB removal and RHAC
yield. Basedon the CCD, a quadratic model and linear modelswere developed for MB
removal and RHAC yield, respectively. The significant factors on each experimental design
responsewere identified from the analysis of variance (ANOVA). The optimum conditions for
RHAC preparation were obtained by using activation time of 4.28 min and microwave power
of 440 W, which resulted MB removal of 83.05% and RHAC yield of 31.98%.
Keywords: Activated carbon, Adsorption, Methylene blue, Microwave heating,Optimization,
Rice husk
Introduction
The textile industry uses dyes to color their product consume large quantities of water
[1]. More than 100,000 commercially available dyes with over 7 x 10
5
tonnes of dyestuff
produced every year have been estimated [2]. At the same time, massive amount of textile
wastewater is produced during dyeing and finishing processes. One of the serious issues
associated with textile wastewater is colored effluent as they produce an obvious color to
water even at low concentration [3]. Therefore, the appearance of dyes onto streams and
rivers are categorized as threatening pollutant that should not be neglected. Indeed, removal
of dyes from the effluent before its disposal in water bodies is very important [4]. In the last
few years, great attention has been placedon utilizing waste as precursor for producing low-
cost activated carbon. In this study an attempt was made to find the optimum preparation
condition of producing activated carbon from rice husk waste.
Methodology
The rice husk was placed in a Pyrex glass reactor in the chamber of the microwave
oven. The microwave irradiation was carried at targeted radiation time and radiation
power under carbon dioxide flow of 150 ml/min as suggested by the Design Expert
software. The response surface methodology (RSM) design known as central composite
design (CCD) was used in this study. The variables involved were microwave power (x
1
)
and activation time (x
2
) with MB removal (y
1
) and RHAC yield (y
2
) as responses. The code
levels for CCD are shown in Table 1.
ISSN: 2638-1974