Journal of Encapsulation and Adsorption Sciences, 2018, 8, 256-279
http://www.scirp.org/journal/jeas
ISSN Online: 2161-4873
ISSN Print: 2161-4865
DOI: 10.4236/jeas.2018.84013 Dec. 20, 2018 256 Journal of Encapsulation and Adsorption Sciences
Review: Low Cost, Environmentally Friendly
Humic Acid Coated Magnetite Nanoparticles
(HA-MNP) and Its Application for the
Remediation of Phosphate from Aqueous Media
Tadewos Damena, Tajeldin Alansi
Applied Chemistry Program, Adama Science and Technology University, Adama, Ethiopia
Abstract
Phosphate is a primary nutrient required for the normal functioning of many
organisms in the ecosystem. However, presence of excess phosphate into the
aquatic systems leads to eutrophication which can promote harmful algal
growth and decrease the amount of dissolved oxygen in water. Municipal,
industrial and agricultural run-off wastewaters are the major point sources
for phosphate discharges. There are different methods to remove phosphates
from water. Among these, adsorption is the most widely accepted method for
phosphate removal because of its high efficiency, minimum cost, easy and
simple operation and applicability at lower concentrations. The emphasis of
this review, is to consolidate low cost, environmentally friendly humic acid
coated magnetite nanoparticles (HA-MNP) and its application for the re-
mediation of phosphate from aqueous media. The magnetic nanoparticles
could be easily separated from the reaction mixture by using a simple hand
held magnet and adsorption studies demonstrate the fast and effective sepa-
ration of phosphate with maximum removal efficiency > 90% at pH 6.6. The
adsorption behavior follows the Freundlich isotherm and the removal of
phosphate is found higher at acidic and neutral pH compared to basic condi-
tions. The nanoparticles exhibit good selectivity and adsorption efficiency for
phosphate in the presence of co-existing ions such as Cl
−
,
2
4
SO
−
and
3
NO
−
with some inhibition effect by
2
3
CO
−
and finally, the effect of temperature on
the adsorption reveals that the process is endothermic and spontaneous.
Keywords
Phosphates, Magnetite Nanoparticle, Humic Acid & Humic Acid Coated
Magnetite Nanoparticle
How to cite this paper: Damena, T. and
Alansi, T. (2018) Review: Low Cost, Envi-
ronmentally Friendly Humic Acid Coated
Magnetite Nanoparticles (HA-MNP) and
Its Application for the Remediation of
Phosphate from Aqueous Media. Journal of
Encapsulation and Adsorption Sciences, 8,
256-279.
https://doi.org/10.4236/jeas.2018.84013
Received: October 4, 2018
Accepted: December 17, 2018
Published: December 20, 2018
Copyright © 2018 by authors and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access