http://www.iaeme.com/IJMET/index.asp 1547 editor@iaeme.com
International Journal of Mechanical Engineering and Technology (IJMET)
Volume 10, Issue 01, January 2019, pp. 1547-1554, Article ID: IJMET_10_01_157
Available online at http://www.iaeme.com/ijmet/issues.asp?JType=IJMET&VType=10&IType=01
ISSN Print: 0976-6340 and ISSN Online: 0976-6359
© IAEME Publication Scopus Indexed
ZINC OXIDE NANOPARTICLES FOR WATER
REMEDIATION IN AGRICULTURE
D. Gnanasangeetha*
Department of Chemistry, PSNA College of Engineering and Technology, Dindigul, Tamilnadu
V. Prathipa
Department of Chemistry, PSNA College of Engineering and Technology, Dindigul,
Tamilnadu, India.
*corresponding author
ABSTRACT
Zinc oxide nanoparticle embedded in activated silica (ZnO-NPs-AS-Ai) as adsorbent
with nano cube shape were synthesized from leaf extract of Acalypha indica via green
method. Adsorbent were characterized using SEM, XRD EDAX and FT-IR. Exploration
shows that the adsorbent is nano cube shape with an average size of 80 nm with elemental
composition of zinc, oxygen and silica with Secondary amine at 2357 cm
-1
and Olefinic
compound at 1600-1450 cm
-1
. The percentage of As (III) removal was very significant at
0.03ppm with arsenic removal of 79.47 to 96.19% with 2g adsorbent dosage at a pH of 6
with a contact time of 60 min and at an agitation speed of 300rpm. Results showed that
the adsorption process by ZnO-NPs-AS-Ai is monolayer chemisorptions. This research
uses existing principles of green chemistry to combat agricultural land contaminated with
arsenic (III) by bioremediation of water to prevent biological magnification.
Key Words: Activated Silica, Adsorbate, Adsorbent, Isotherm and Kinetics, Zinc oxide
Nanoparticles
Cite this Article: D. Gnanasangeetha and V. Prathipa, Zinc Oxide Nanoparticles for Water
Remediation in Agriculture, International Journal of Mechanical Engineering and
Technology, 10(01), 2019, pp.1547–1554
http://www.iaeme.com/IJMET/issues.asp?JType=IJMET&VType=10&Type=01
1. INTRODUCTION
Green synthesis of nanoparticle for water remediation using plants is in the exploitation by
researchers. Nanotechnology applications are highly suitable for biological molecules, because
of their exclusive properties. Although chemical method of synthesis requires short period of time
for synthesis of large quantity of nanoparticles, this method requires capping agents for size
stabilization of the nanoparticles. Chemicals used for nanoparticles synthesis and stabilization
are toxic and lead to non-ecofriendly by products [1]. Green nanotechnology has goals to produce
nanomaterials and products without harming the environment or human health and produce nano