ISSN: 2410-9649 Siddique et al / Chemistry International 4(1) (2018) 1-6 iscientic.org.
1
www.bosaljournals/chemint/ editorci@bosaljournals.com
Article type:
Research article
Article history:
Received June 2017
Accepted October 2017
January 2018 Issue
Keywords:
Pollution
Metals
Rocks
Nutrients
Spectroscopy
Photometry
This study focuses on fundamental scrutiny of phosphate rock samples in order
to investigate the elemental composition (Zinc, Cadmium, Lead, Sodium and
Potassium) by Flame Photometry & Atomic Absorption Spectroscopy. The
samples have been collected from Hazara Division, Khyber Pakhtunkhwa (KPK),
Peshawar. Relative study on heavy metal content and nutrients was performed to
find out the comparative resources quality. The sample S5 exhibits highest
Cadmium contents while S6 shows higher concentration of other metals. The
local resources indicate higher quantity of Lead (Pb). The remedy for this
excessive amount of Pb may probably be done by complete separation and
disposal of waste phosphogypsum. The phosphate rocks found in the region are
good enough to be utilized as raw material for fertilizer manufacturing plants.
© 2018 International Scientific Organization: All rights reserved.
Capsule Summary: The elemental analysis of heavy metals and nutrients was performed atomic absorption spectroscopy to
determine phosphate rock quality in Pakistan.
Cite This Article As: A. Siddique, A. Hassan, S. R. Khan, A. Inayat, A. Nazir and M. Iqbal. Appraisal of heavy metals and nutrients
from phosphate rocks, Khyber Pakhtunkhwa, Pakistan. Chemistry International 4(1) (2018) 1-6.
INTRODUCTION
Phosphate is generally employed for the manufacturing of
fertilizers. It is the minor constituent of many products like
light bulbs, toothpastes, flame-resistant fabrics, detergent
manufacturing, livestock and poultry feed etc. (Javied et al.,
2008; Mar and Okazaki, 2012; Huang et al., 2017).
Phosphate rock (PR) is natural mineral deposits belongs to
the species of apatite family. Apatite is a primary phosphate
mineral that can differ significantly in physical, chemical,
and crystallographic properties (Ahialey et al., 2014; Liu et
al., 2017).
Mostly PR deposits include variety of carbonate-
fluorapatite, grouped under the collective name of
francolite. Sedimentary phosphate deposits display varying
compositions and physical forms and found in formations
from different ages (Abouzeid, 2008; Dargahi et al., 2016).
Igneous phosphates include silica deficient intrusions. The
apatite linked with these rocks may probably be of a
primary magmatic and hydrothermal or secondary origin.
The guano type phosphate deposits are the best known
natural fertilizers due to extraordinarily higher quantity of
nutrients like nitrogen (N), phosphate PO4
3-
and potassium
(K) vital for plant development. Guano type rock
Chemistry International 4(1) (2018) 1-6
Appraisal of heavy metals and nutrients from phosphate rocks, Khyber
Pakhtunkhwa, Pakistan
Abubakar Siddique
1
, Abida Hassan
2
, Shahid Rehman Khan
3
, Asma Inayat
3
, Arif Nazir
1,
* and
Munawar Iqbal
1
1
Department of Chemistry, University of Lahore, Lahore-Pakistan
2
Department of Chemistry, Govt. College of Science Wahdat Road, Lahore-Pakistan
3
Applied Chemistry Research Centre, PCSIR Labs Complex Ferozepur Road, Lahore-Pakistan
*Corresponding Author Email: anmalik77@gmail.com
ARTICLE INFO ABSTRACT