© July 2019 | IJIRT | Volume 6 Issue 2 | ISSN: 2349-6002
IJIRT 148468 INTERNATIONAL JOURNAL OF INNOVATIVE RESEARCH IN TECHNOLOGY 140
An Innovative Approach to the Extraction of Humic Acid
from Cow Dung- A Case Study
Somalika Pradhan
1
, Jitendra Pramanik
2
1
Lecturer, Centurion University of Technology & Management, Bhubaneswar, India
2
Assistant professor, Centurion University of Technology & Management, Bhubaneswar, India
Abstract- Intense utilization of humic substances in
agriculture has generated a lot of interest among
producers, consumers & regulators for an accurate,
reliable & cost effective method to quantify humic acid
in raw ores & products. Humic acids are dark coloured
fully decomposed remains of plant and animal organic
matter. They play a leading role in several chemical,
geochemical and geological processes. Humic substances
also promote plant growth and improve the organic
matter status of soil and soil fertility. Here we present a
thoroughly validated method for the extraction of
humic acid from dry cow dung powder. The proposed
methodology is found to be simple, cost effective, and
eco-friendly. The process investigated herein provides a
promising solution to many global environmental
problems.
Index terms- Humic acid, Extraction Procedure,
Ultraviolet-visible spectroscopy
I. INTRODUCTION
Humic substances (HS) the most ubiquitous natural
organic materials present in soils, sediments and
water as a product of the chemical and biological
transformation of animal and plant residues [1].
Humic substances are yellow to black in colour with
a wide range of molecular weights. Humic substances
serve as substrate for microorganism growth on the
other hand they have very strong chelate ability with
many heavy metals and organic pollutants, which
make these toxins more difficult to be removed. As a
result of which HS strongly influence the
environmental fate of hydrophobic organic chemicals
in soils and sediments. Humic substances have a
profound influence on the biogeochemical cycles of
both natural and anthropogenic constituents [2].
Based on the solubility of humic substances in
aqueous solution, these are operationally divided into
three different fractions: (i) Humic acid (HA), the
fraction soluble at alkaline pH values; (ii) Fulvic acid
(FA), the fraction soluble at all pH values; and (iii)
Humin, the fraction insoluble at all pH values with
the average properties and structure of a large
assembly of components of diverse structure and
molecular weight [3].
Humic acid is the fraction of humic substance which
is insoluble in water under acidic condition (pH < 2)
and is a poly-disperse macromolecule comprising of
amino acids, amino sugars, peptides and aliphatic
compounds etc. Humic acid is being employed in
varied facets veterinary medicine, in agriculture,
industries, environment, and even in medicine. HA is
known to play a vital role as a chemotherapeutic
agent and exhibits anti-viral, anti-microbial, anti-
inflammatory, and anticoagulant properties.
A derivative of HA has potent HIV-1 3 and Herpes
inhibiting properties. HA impounds on anthropogenic
organic compounds, photosensitizes chemical
reactions. HA also complexes with heavy metals as
well as with carcinogens.
Fig-1 (Model structure of humic acid according to
Stevenson-4)
Humic acid originates mostly in the abiotic niche of
the lithosphere and hydrosphere due to the
humification of biodegradable entities. Parameters to
which humification is highly sensitive are pH,
temperature, and climatic conditions. In case of any
difference in geographical origin, some degrees of