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Current Drug Delivery, 2016, 13, 000-000 1
RESEARCH ARTICLE
1567-2018/16 $58.00+.00 © 2016 Bentham Science Publishers
Chitosan-Hydroxypropyl Methylcellulose Matrices as Carriers for Hydro-
dynamically Balanced Capsules of Moxifloxacin HCl
Anurag Verma
1
, Juhi Dubey
1
, Navneet Verma
1
and Amit Kumar Nayak
2,*
1
Department of Pharmaceutics, College of Pharmacy, IFTM University, Lodhipur Rajput, Delhi Road, Moradabad-244
001, U.P., India;
2
Department of Pharmaceutics, Seemanta Institute of Pharmaceutical Sciences, Jharpokharia, Ma-
yurbhanj-757086, Odisha, India
A R T I C L E H I S T O R Y
Received: March 31, 2016
Revised: May 13, 2016
Accepted: May 19, 2016
DOI:
10.2174/2213476X03666160525144
455?
Abstract: Background: In recent years, gastroretentive, hydrodynamically balanced
system (HBS) for stomach-specific floating sustained drug release has gained a lot of
importance in improving absorption of drugs especially those absorbed from stom-
ach and small intestine.
Objective: The objective of the current investigation is to evaluate chitosan-
hydroxypropyl methylcellulose (HPMC) based on polymeric matrices as a carrier for
single-unit capsules based on HBS for stomach-specific floating sustained drug re-
lease using moxifloxacin HCl (MX) as a model drug.
Method: Various HBS capsules of MX were prepared by physical blending of MX
with chitosan (low or medium molecular mass) or HPMC (K4M or K15M) or chitosan-HPMC combi-
nations in varying proportions followed by encapsulation into size 0 capsules made of hard gelatin. The
in vitro buoyancy and drug release in 0.1 N HCl (pH 1.2) were evaluated.
Results: HBS capsules based on chitosan (low and medium molecular weight and their combination) as
polymer matrix failed to float on 0.1 N HCl (pH 1.2). Whereas, formulations containing HPMC (K4M
or K15M) or their mixture with chitosan, remained buoyant and released MX over 9 h in the acidic dis-
solution medium following zero-order kinetics.
Conclusion: HPMC (K4M, K15M, blend of K4M and K15M) or their mixture with low/medium mo-
lecular mass chitosan may constitute excellent carrier systems for the stomach-specific sustained deliv-
ery of MX over a longer period.
Keywords: Chitosan, drug release, HPMC, hydrodynamically balanced system.
1. INTRODUCTION
A considerable interest has recently been spotlighted on
the potential applications of natural as well as synthetic bio-
degradable and biocompatible polymeric materials as matri-
ces for sustained oral drug delivery [1-3]. Among various
biodegradable and biocompatible polymers, chitosan and
hydroxypropyl methylcellulose (HPMC) have received spe-
cial attention. Chitosan (deacetylated chitin) is one of the
biologically derived cationic polysaccharides, which is re-
garded as a ‘Generally Recognized as Safe’ (GRAS) material
and has also been utilized in the development of several
pharmaceutical dosage forms [4, 5]. During the last few dec-
ades, chitosan has appeared as a suitable biopolymer for the
delivery of drugs because of its excellent physicochemical,
biological as well as pharmaceutical characteristics [6-10].
*Address correspondence to this author at the Department of Pharmaceutics,
Seemanta Institute of Pharmaceutical Sciences, Mayurbhanj-757086, Od-
isha, India; Te: +91-9583131603; E-mail: amitkrnayak@yahoo.co.in
Currently, chitosan based dosage forms for oral administra-
tion have widely been examined for their ability of these
systems to localize at the desired-sites like stomach for the
delivery of drugs to increase the contact time of the tissue
surface of gastrointestinal tract (GIT) to get better permeabil-
ity of drugs [11, 12]. In addition, chitosan has mucoadhesive
ability on to the stomach mucosa resulting in stronger con-
tact with the site of delivery [13, 14]. Also, HPMC has
global regulatory acceptance for use in development of vari-
ous pharmaceutical preparations [15, 16]. It is biocompatible
and composed of alkylhydroxy, alkylcellulose ether with
hydroxypropyl and methoxyl groups. As it is a nonionic wa-
ter-soluble polymer, the probability of chemical interactions
between ingredients is very much decreased. The polymeric-
matrices made up of HPMC also exhibit pH-independent
release of drugs [16, 17]. The aqueous solution of HPMC is
stable enough over wider pH-range and is also resistant to
enzymatic-degradation. These properties make HPMC as
one of the most popular biopolymers for matrix application.
A.K. Nayak