153
Mutagenesis, 2019, 34, 153–164
doi:10.1093/mutage/gez004
Original Manuscript
Advance Access publication 10 March 2019
© The Author(s) 2019. Published by Oxford University Press on behalf of the UK Environmental Mutagen Society.
All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.
Original Manuscript
The processes associated with lipid
peroxidation in human embryonic lung
fbroblasts, treated with polycyclic aromatic
hydrocarbons and organic extract from
particulate matter
Pavel Rossner, Jr.
1,
*, Helena Libalova
1
, Tereza Cervena
1,2
, Kristyna Vrbova
1
,
Fatima Elzeinova
1
, Alena Milcova
1
, Andrea Rossnerova
1
,
Zuzana Novakova
1
, Miroslav Ciganek
3
, Michaela Pokorna
1
,
Antonin Ambroz
1
and Jan Topinka
1
1
Department of Genetic Toxicology and Nanotoxicology, Institute of Experimental Medicine of the Czech Academy of
Sciences, Prague 14220, Czech Republic,
2
Department of Physiology, Faculty of Science, Charles University, Prague,
Czech Republic,
3
Department of Chemistry and Toxicology, Veterinary Research Institute, Brno 62100, Czech Republic
*To whom correspondence should be addressed. Pavel Rossner, Jr., Department of Genetic Toxicology and Nanotoxicol-
ogy, Institute of Experimental Medicine of the Czech Academy of Sciences, Videnska 1083, Prague 14220, Czech Republic.
Tel: +420 241062596; Email: pavel.rossner@iem.cas.cz
Received 10 December 2018; Revised 29 January 2019; Editorial decision 29 January 2019; Accepted 1 February 2019.
Abstract
Polycyclic aromatic hydrocarbons (PAHs) may cause lipid peroxidation via reactive oxygen species
generation. 15-F
2t
-isoprostane (IsoP), an oxidative stress marker, is formed from arachidonic acid
(AA) by a free-radical induced oxidation. AA may also be converted to prostaglandins (PG) by
prostaglandin-endoperoxide synthase (PTGS) induced by NF-κB. We treated human embryonic lung
fbroblasts (HEL12469) with benzo[a]pyrene (B[a]P), 3-nitrobenzanthrone (3-NBA) and extractable
organic matter (EOM) from ambient air particulate matter <2.5 µm for 4 and 24 h. B[a]P and 3-NBA
induced expression of PAH metabolising, but not antioxidant enzymes. The concentrations of IsoP
decreased, whereas the levels of AA tended to increase. Although the activity of NF-κB was not
detected, the tested compounds affected the expression of prostaglandin-endoperoxide synthase
2 (PTGS2). The levels of prostaglandin E
2
(PGE
2
) decreased following exposure to B[a]P, whereas
3-NBA exposure tended to increase PGE
2
concentration. A distinct response was observed after
EOM exposure: expression of PAH-metabolising enzymes was induced, IsoP levels increased
after 24-h treatment but AA concentration was not affected. The activity of NF-κB increased after
both exposure periods, and a signifcant induction of PTGS2 expression was found following 4-h
treatment. Similarly to PAHs, the EOM exposure was associated with a decrease of PGE
2
levels.
In summary, exposure to PAHs with low pro-oxidant potential results in a decrease of IsoP levels
implying ‘antioxidant’ properties. For such compounds, IsoP may not be a suitable marker of lipid
peroxidation.
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