March 2020 | Vol. 48 | No. 1
Microbiol. Biotechnol. Lett. (2020), 48(1), 12–23
http://dx.doi.org/10.4014/mbl.1909.09016
pISSN 1598-642X eISSN 2234-7305
Microbiology and Biotechnology Letters
Enhancement of β-cyclodextrin Production and
Fabrication of Edible Antimicrobial Films Incorporated
with Clove Essential Oil/β-cyclodextrin Inclusion
Complex
Mohamed G. Farahat*
Botany and Microbiology Department, Faculty of Science, Cairo University, 12613 Giza, Egypt
Received: October 1, 2019 / Revised: November 24, 2019 / Accepted: November 26, 2019
Introduction
Microbial contamination of food products accelerates
the deterioration process and increases the risk of food-
borne illness caused by potentially life-threatening
pathogens. Ordinarily, food contamination originates
superficially therefore, proper surface treatment and
packaging is crucial for assuring food quality and safety
[1]. Recently, edible films have gained much interest in
preserving various food products, retaining their
firmness and restricting weight loss that occurs due to
loss of moisture [2-4]. Chitosan is an abundantly
available biodegradable polysaccharide that demon-
strates remarkable film-forming properties [5-7].
Furthermore, the edible films could be used as a vehicle
for additives such as antioxidants and antimicrobials,
Edible films containing antimicrobial agents can be used as safe alternatives to preserve food products.
Essential oils are well-recognized antimicrobials. However, their low water solubility, volatility and high
sensitivity to oxygen and light limit their application in food preservation. These limitations could be
overcome by embedding these essential oils in complexed product matrices exploiting the encapsulation
efficiency of β-cyclodextrin. This study focused on the maximization of β-cyclodextrin production using
cyclodextrin glucanotransferase (CGTase) and the evaluation of its encapsulation efficacy to fabricate edible
antimicrobial films. Response surface methodology (RSM) was used to optimize CGTase production by
Brevibacillus brevis AMI-2 isolated from mangrove sediments. This enzyme was partially purified using a
starch adsorption method and entrapped in calcium alginate. Cyclodextrin produced by the immobilized
enzyme was then confirmed using high performance thin layer chromatography, and its encapsulation effi-
ciency was investigated. The clove oil/β-cyclodextrin inclusion complexes were prepared using the co-
precipitation method, and incorporated into chitosan films, and subjected to antimicrobial testing. Results
revealed that β-cyclodextrin was produced as a major product of the enzymatic reaction. In addition, the
incorporation of clove oil/β-cyclodextrin inclusion complexes significantly increased the antimicrobial
activity of chitosan films against Staphylococcus aureus, Staphylococcus epidermidis, Salmonella
Typhimurium, Escherichia coli, and Candida albicans. In conclusion, B. brevis AMI-2 is a promising source
for CGTase to synthesize β-cyclodextrin with considerable encapsulation efficiency. Further, the obtained
results suggest that chitosan films containing clove oils encapsulated in β-cyclodextrin could serve as edi-
ble antimicrobial food-packaging materials to combat microbial contamination.
Keywords: β-cyclodextrin glucanotransferase, Brevibacillus, RSM, optimization, immobilization
*Corresponding author
Tel: +20-1116080701, Fax: +20-235727556
E-mail: farahat@cu.edu.eg
© 2020, The Korean Society for Microbiology and Biotechnology