International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-6, Issue-11, Nov-2020]
https://dx.doi.org/10.22161/ijaems.611.1 ISSN: 2454-1311
www.ijaems.com Page | 456
Thermal regeneration of activated carbon
saturated with nitrate ions from an artisanal
furnace
Horo Koné
1
, Konan Edmond Kouassi
2
, Affoué Tindo Sylvie Konan
1
, Kopoin
Adouby
1
, Kouassi Benjamin Yao
1
1
Laboratoire des Procédés Industriels, de Synthèse de l’Environnement et des Energies Nouvelles (LAPISEN); Institut National
Polytechnique Houphouët-Boigny, BP 1313 Yamoussoukro, Côte d’Ivoire
2
Laboratoire de Thermodynamique et de Physico-Chimie du Milieu (LTPCM), UFR-SFA, Université Nangui-Abrogoua, 02 BP 801
Abidjan 01, Cote d’Ivoire
Received: 11 Oct 2020; Received in revised form: 06 Nov 2020; Accepted: 09 Nov 2020; Available online: 11 Nov 2020
©2020 The Author(s). Published by Infogain Publication. This is an open access article under the CC BY license
(https://creativecommons.org/licenses/by/4.0/).
Abstract— The present study was initiated to help the simple and less expensive regeneration of activated
carbons after saturation in rural area. In order to determine a regeneration time and the number of
regeneration cycles, an adsorption test was necessary. Thus, 3h and 4 cycles of carbon regeneration are
obtained after evaluation of the performance, percentage and adsorption capacity after each cycle.
Regeneration percentages of 71.29, 54.05, 40.40, 28.06 % and 72.6, 69.84, 64.33, 34.98 %for respective
concentrations of 30± 1.2 mg/L and 55 ± 1.6 mg/L are observed. Also, the performances of activated
carbon 8.5, 10, 12, 20 g/L and capacities 24.04, 19.93, 14.9 and 10.35mg/g 35.7, 34.12, 31.43 and 17.09
mg/g respectively for dry season and rainy season were necessary to fix the number of cycles. The
artisanal furnace with its ease of installation and its maximum temperature of 500±2°C is suitable for the
regeneration of saturated activated carbon.
Keywords— Regeneration, saturated activated carbon, artisanal furnace.
I. INTRODUCTION
Sustainable development necessarily
involves recycling everything we use in order to guarantee
the life for future generations. It is in this perspective that
researchers have taken an interest in the regeneration of
activated carbon in order to protect what the forerunners
used in their productions. Several regeneration methods
are available. It can be extractive using a volatile organic
solvent [1], a fluid such as CO2 [2] or concentrated
solutions of surfactants [3], to extract the pollutants from
the activated carbon. However, its implementation remains
costly even if this opinion is not unanimous. Indeed, some
estimates consider it much cheaper than thermal
regeneration [4,5]. Regeneration can be done in the same
way by vapour desorption with the use of temperatures
between 105 and 140 °C [6] to just shift the adsorption
equilibrium. Like the first mentioned, it is limited for
activated carbons having adsorbed volatile compounds. In
addition to the two methods, thermal regeneration, which
is the most common method, perfectly regenerates the
activated carbon [7]. [8] reported percentages of 92-95%
and 96-98% regeneration for carbons regenerated at
500°C. In addition, this method leads to a mass loss of coal
in the order of 7-10%, and can reduce the porosity of the
adsorbent [9]. Also, certain bacteria and enzymes are
involved in the regeneration of activated carbons. In this
way, bacteria or micro-organisms that can degrade the
pollutant are brought into contact with the carbon [5]. This
method is limited in the presence of poorly biodegradable
pollutants or when concentration levels reach the
inhibition or toxicity threshold [10]. Electrolytes can be
used for electrochemical regeneration. [11] and [12] have
used NaCl, Na2SO4 or NaHCO3 as electrolytes,
respectively. [13] in using the electrochemical route, have
reported a regeneration percentage ranging from 70 to 90%