International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 08 Issue: 01 | Jan 2021 www.irjet.net p-ISSN: 2395-0072
© 2021, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 474
GEOPOLYMER CONCRETE WITH FLYASH AND GGBS
Ashwini Kumar
1
, Pradyumna Dashora
2
1
M.Tech. Student, Department of Civil Engineering, Pacific Academy Of Higher Education And Research University,
Udaipur, Rajasthan, India
2,
Assistant Professor, Department of Civil Engineering, Pacific Academy Of Higher Education And Research University,
Udaipur, Rajasthan, India
-------------------------------------------------------------------------***----------------------------------------------------------------------
Abstract:-Construction has been most important human
activity since ancient time. Concrete is widely used and
reliable material for construction. Some of challenges in
industry are global warming and insufficiency of
construction material. One of the methods for replacing
concrete constituents is the use of geo-polymer which
helps in using very less quantity of cement in concrete.
This project represents study on the mechanical properties
of geopolymer concrete with various mixes.
In this study, Geopolymer concrete is produced with fly
ash and sodium hydroxide and sodium silicate is used as a
binder. Fly ash is replaced by GGBS in proportions of 25%,
50% and 75% to enhance various properties of concrete.
For this project, the mix design is carried out for 11M and
13M concentration of sodium hydroxide. Alkaline activator
solution ratio of 2.5 and alkaline liquid to fly ash ratio 0.40
is selected for this investigation.
The specimen of size 150x150x150mm cubes,
150x300mm cylinders and 500x100x100mm prisms were
casted and the specimens of geo-polymer concrete are
cured at ambient temperature for 7 days and 28 days. The
cured specimens were then tested for compressive
strength, split tensile strength and flexural strength
respectively.
Keywords-Fly Ash, Ground Granulated Blast Slag,
Geopolymer concrete, Sodium Hydroxide, Sodium
Silicate, Molarity.
1. INTRODUCTION
Geopolymer is an inorganic alumina-silicate
polymer synthesized predominantly from silicon and
aluminum material such as fly ash and GGBS (Ground
granulated blast furnace slag). The binders could be
produced by a polymeric reaction of alkaline solutions
with materials containing silicon and aluminum by
geological origin or by- product materials such as fly ash
and GGBS.
The major component in ordinary Portland
cement (OPC) is calcium silicate hydrate (C–S–H). The
crystalline form of (C–S–H) consists of a layered structure
where chains of silicon oxide tetrahedral sandwich a CaO
layer and alternate with water interlayer. Calcium
preferentially binds with silicate during the reaction of
SiO
2
, CaO, and water to quickly and easily form the stable
C–S–H product, which allows OPC to be a quick-setting
material. However, OPC production is considered
environmentally unfriendly, because it requires large
quantities of raw materials and fuel and it releases dusts
and CO
2
(a greenhouse gas). In addition, OPC is not
chemically stable, deteriorating through carbonation and
dehydration.
Geopolymers (GPs) are amorphous to semi-
crystalline alumino silicates with short range, local
ordering similar to that of zeolites. Silicon and aluminum
oxide tetrahedral are linked together to create a negatively
charged, three- dimensional, porous framework where the
pores are filled with counter-balancing cations, Group I or
II, and water molecules. GPs are considered environmental
friendly products because they can use waste materials
such as fly ash (FA) for their production and reduce
greenhouse gas emissions. In addition, they exhibit high
mechanical strength and stability and they are acid and fire
resistant. However, GPs do not always set-up as quickly as
OPCs.
While there are many differences between OPCs
and GPs, the main difference is the absence of calcium
within the geopolymer structure. Thus, many researchers
have investigated the effects of adding calcium into their
geopolymer syntheses through various forms such as
ground granulated blast furnace slag (a high-calcium
source), high- calcium Class C FA, calcium salt solutions,
Ca(OH)
2
, and CaO. Incorporation of such various forms of
calcium into a traditional geopolymer synthesis will lead to
different reaction pathways and the formation of multiple
reaction products such as C–S–H, calcium aluminates
hydrate (CAH), calcium alumino silicate hydrate (CASH),
various calcium silicate phases, and Ca-geopolymer in
addition to the expected Group I geopolymer product. Yip
and coworkers, for example, incorporated slag into their
metakaolin (MK) GPs. Under certain conditions and
alkaline-ities, distinct geopolymer and C–S–H phases
coexisting within the sample were observed. However, at
high slag concentrations, only C–S–H,CAH, and CASH