ARTICLE IN PRESS
G Model
CULHER-3890; No. of Pages 14
Journal of Cultural Heritage xxx (xxxx) xxx–xxx
Available online at
ScienceDirect
www.sciencedirect.com
Original article
Research into the influence of subsoil on sulphates, nitrates and
chlorides accumulated in renovation plasters used for rehabilitation
of monuments in the Czech Republic
Martina Peˇ rinková
a
, Ivona Dlábiková
a,∗
, Pavel Pospíˇ sil
b
, Vlastimil Bílek
c
a
Technical University of Ostrava, Faculty of Civil Engineering, Department of Architecture, Ludvíka Podéˇ stˇ e 1875/17, 708 33 Ostrava – Poruba, Czech
Republic
b
Technical University of Ostrava, Faculty of Civil Engineering, Department of Geotechnics and Underground Engineering, Ludvíka Podéˇ stˇ e 1875/17, 708 33
Ostrava – Poruba, Czech Republic
c
Technical University of Ostrava, Faculty of Civil Engineering, Department of Building Materials and Diagnostics of Structure, Laboratory of Building
Materials, Ludvíka Podéˇ stˇ e 1875/17, 708 33 Ostrava – Poruba, Czech Republic
a r t i c l e i n f o
Article history:
Received 3 June 2020
Accepted 28 January 2021
Available online xxx
Keywords:
Renovation plasters
Historical masonry
Masonry salinity
Sulphates
Subsoil
a b s t r a c t
Degradation of historical masonry and plasters is often caused by external conditions; the presented
research focused on salts originating from subsoils. The content of salts: Sulphates, Nitrates and Chlorides
was analysed from plasters on 5 chosen historic buildings before and after the renovation in this paper. The
samples were collected three times between 1998−2018. In some cases, the Sulphates were still present
or even with a higher content after the renovation in comparison with the state before renovation. That
can be caused by many factors from environment and this work focused on source from the subsoil. To
understand better geological background the borehole data around each object were studied. According
boreholes were buildings divided in two groups: on clayey subsoil and building on subsoil without clay.
By Kruskal–Wallis test was proved, that the Sulphates content in plasters was constant before and after
the renovation on clayey subsoils, it didn´ t changed in a time. On subsoils without clay (mainly silty
to sandy soils) the content of Sulphates declined after the renovation, what was proved by regression
analyse on 95% confidence level.
© 2021 Elsevier Masson SAS. All rights reserved.
1. Introduction
The issue of damage to historical masonry by salt crystalliza-
tion in the pore systems of artificially made ceramic materials,
natural stones or plasters has long been known as it affects his-
torical buildings. The salts usually originate from the subsoil, from
where they naturally migrate in solutions. Movement of the saline
solutions depends on many factors. The essential aspect is the
chemical composition of the salts, which determines their solubil-
ity, migration and conditions of crystallization in case of decreased
humidity/moisture. From the geochemical point of view, the pro-
cess is affected by the composition of a subsoil structure; from
the hydrogeological point of view, the groundwater level and the
nature of the subsoil’s pore system in the capillary fringe above
∗
Corresponding author at: Mateja Bela, 8768/28, 01015
ˇ
Zilina, Slovakia.
E-mail addresses: martina.perinkova@vsb.cz (M. Peˇ rinková),
ivona.dlabikova@gmail.com (I. Dlábiková), pavel.pospisil@vsb.cz (P. Pospíˇ sil),
vlastimil.bilek@vsb.cz (V. Bílek).
groundwater level and in the aerated zone dominate, and humidity
varies depending on the amount of rainwater falling on the ground
in the broader proximity of the structure.
Many authors have dealt with the degradation process of his-
torical masonry, e.g., Winkler [1] provided a complex assessment
of the degradation of natural stones in historical structures, Goudie
and Viles [2] and Rodriguez-Navarro and Doehne [3] focused on the
effect of various types of salts on construction materials, while Laue
[4] assessed material erosion due to the effect of salts in relation to
the climate in which the structures are located.
The most harmful salts are often highly soluble in water and are
transported by water inside porous material [5]. WTA specifies the
classification of the salt content in the material at three levels: low,
medium and high [6,7]. Damage to porous construction material is
usually caused by physical and chemical processes (especially crys-
tallization pressure). The process is linked to decreased moisture of
the porous material and fluctuation of relative air humidity in prox-
imity to the structure. This results in a transition from liquid to solid
salt state, i.e., in crystallization. Restoration procedures to renovate
and protect porous materials affected by salt-related degradation
https://doi.org/10.1016/j.culher.2021.01.011
1296-2074/© 2021 Elsevier Masson SAS. All rights reserved.
Please cite this article as: M. Peˇ rinková, et al., Research into the influence of subsoil on sulphates, nitrates and chlorides
accumulated in renovation plasters used for rehabilitation of monuments in the Czech Republic, Journal of Cultural Heritage,
https://doi.org/10.1016/j.culher.2021.01.011