RESEARCH ARTICLE
Modeling of polymer electrolyte membrane fuel cell with
circular and elliptical cross‐section gas channels: A novel
procedure
Nima Ahmadi
1,2
| Abdolrahman Dadvand
2
| Iraj Mirzaei
2
| Sajad Rezazadeh
2
1
Department of Mechanical Engineering,
Faculty of Shaheed Beheshti, Technical
and Vocational University (TVU), Urmia,
Iran
2
Faculty of Mechanical Engineering,
Urmia University of Technology, Urmia,
Iran
Correspondence
Nima Ahmadi, Faculty of Mechanical
Engineering, Urmia University of
Technology, Urmia, Iran.
Email: nima.ahmadi.eng@gmail.com
Summary
The main objective of this paper is to develop an analytical solution based on
the perturbation method to solve the continuity and momentum equations
governing the flow in gas channels of a PEMFC having circular and elliptical
cross sections. The equations are solved in both the anode and cathode gas
channels with appropriately defined perturbation parameters to obtain the
velocity profile in these channels. It was observed that by changing the circular
cross section to an elliptical one (ie, increasing the value of perturbation
parameter), the axial velocity increases. As a result, the penetration of species
into the reaction areas decreases. Then, the effect of species penetration speed
on the performance of PEMFC is discussed. Increasing the penetration speed
(ie, radial velocity) of the reactant gases causes the maximum value of the gas
velocity in the channel to decrease. This would imply that the diffusion rate
of the reactant species to the reaction areas, and thereby the cell performance
would be optimized. Apart from the analytical solution, 3‐D numerical solution
of the governing equations using collocated finite volume method along with
the SIMPLE algorithm is also performed. The results are validated against the
available published data. The numerical results confirm that by converting
the circular cross section to the elliptical one, while other conditions are fixed,
the PEMFC produces less current density.
KEYWORDS
analytical solution, numerical procedure, PEMFC, performance, perturbation method
1 | INTRODUCTION
Among the energy conversion devices, the fuel cell is a
promising future energy resource. Among the various
types of fuel cells, the polymer electrolyte membrane fuel
cell (PEMFC) is of great importance due to its high power
density. In this system, the electrochemical energy is
converted to the electrical energy.
1-4
A typical PEMFC
Nomenclature: Re, Reynolds number; U, Average velocity of fluid flow [dimensionless]; F, Faraday constant [C/mol]; I, Local current density [A/m
2
];
C, Mass fraction; ω, Porosity [dimensionless]; D
eff
, Mass diffusion coefficient [m
2
/s]; S, Source term; T, Temperature [K]; κ
eff
, Electrode electronic
conductivity (S/m); Φ, Phase potential [V]; V
cell
, Cell voltage [volt]; r, Radius [Dimensionless]; θ, Angle [dimensionless]; ε, Perturbation parameter
[dimensionless]; P, Pressure [Pa]; u
!
, Velocity vector [m/s]; PEMFC, Protonic electrolyte membrane fuel cell; μ, Viscosity [kg/m·s]; ρ, Density (kg/
m
3
); γ
eff
, Effective electrode thermal conductivity (W/m/K)
Subscripts: eff, Effective; In, Inlet; m, Mass; mom, Momentum; sol, Solid phase; mem, Membrane phase
Received: 4 January 2018 Revised: 17 February 2018 Accepted: 3 March 2018
DOI: 10.1002/er.4069
Int J Energy Res. 2018;1–18. Copyright © 2018 John Wiley & Sons, Ltd. wileyonlinelibrary.com/journal/er 1