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International Journal of Scientific Research in Science and Technology
Print ISSN: 2395-6011 | Online ISSN: 2395-602X (www.ijsrst.com)
doi : https://doi.org/10.32628/IJSRST207667
7
Synthesis, Characterization and Biological Active 2 (Dimethylamino)
Cyclohexane-1, 3-Dione
Veerappan Jeyachandran
Department of Chemistry, Bharath Institute of Higher Education and Research, Selaiyur, Chennai, Tamil Nadu,
India
Corresponding author e-mail: jeyorg@gmail.com
Article Info
Volume 8, Issue 1
Page Number: 07-09
Publication Issue :
January-February-2021
Article History
Accepted : 01 Jan 2021
Published : 04 Jan 2021
ABSTRACT
In the present work, the precursors 2- ( ( dimethylamino ) methylene )
cyclohexane-1,3-dione 4 and 2- ( ( dimethylamino ) methylene ) -5, 5-
dimethylcyclohexane-1,3-dione 5 were synthesized from the reaction of 1,3-
cyclohexanedione 1 or 5,5-dimethyl-1,3-cyclohexandione 2 with DMF-DMA 3,
respectively following literature procedure (Scheme 1).
Seheme 1. Synthesis of precursors 4, 5
Keywords : Pyrazoles, Dimethylamino, Cyclohexane and Alkaloids.
I. INTRODUCTION
Pyrazoles are five-member ring heterocyclic
compounds, consisting of a doubly unsaturated five
membered ring with two adjacent nitrogen atoms and
are also called as azoles. These are aromatic molecules
due to their planar conjugated ring structures with six
delocalized π-electrons [1]. The term pyrazole was
given by Ludwig Knorr in 1883. Being so composed
and having pharmacological effects on humans, they
are classified as alkaloids, although they are rare in
nature. In 1959, the first natural pyrazole, β-[1-
pyrazolyl] alanine was isolated from the seeds of
water melons [Citurllus lanatus] [2]. Literature
survey has revealed that till 1930s very little had been
done for the synthesis of steroidal pyrazole
derivatives. Several pyrazole derivatives have been
found to possess significant activities such as 5-α-
reductase inhibitor, [3] antiproliferative, [4]
antiparasitiC [5] and herbicides [6].
pyrazolo[1,5-a] quinoline derivatives have been
developed for dopamine D4 antagonist agents,[7]
GPR109a agonist agents [8] and organic light-