Desalination 193 (2006) 422–425
0011-9164/06/$– See front matter © 2006 Published by Elsevier B.V.
Presented at the International Congress on Membranes and Membrane Processes (ICOM), Seoul, Korea,
21–26 August 2005.
*Corresponding author.
Use of membranes in copper hydrometallurgy
N. Sabba
a
, D.E. Akretche
b
*
a
Faculty of Chemical Engineering,
b
Faculty of Chemistry, USTHB, BP32, El-Alia, 16111 Bab Ezzouar, Algiers, Algeria
Fax +213 (21) 247311; email: dakretche@hotmail.com
Received 22 March 2005; accepted 28 August 2005
Abstract
Usually, the recovery of metals from ore follows a flow sheet which includes the leaching operation, the filtration
and the purification concentration. However, in this work a new processing method is described. It is an
electromembrane process where the ore is inserted between two membranes. It is shown that an application of a
current density gives rise to an efficiency recovery of copper using ion exchange membranes.
Keywords: Hydrometallurgy; Electroleaching; Ion-exchange membranes
1. Introduction
The recovery of metals from non-ferrous ores
has been widely studied and the process chosen
depends upon both the composition and the
localization of the ore. Hydrometallurgical tech-
niques are often used knowing the low metal con-
centration in the actual sources. Thus, leaching is
the principal operation of the process and many
works are performed to improve extraction yields,
economical aspects and the selectivity.
Recently, new developments of electro-mem-
brane processes in solid matrix treatment, par-
ticularly in soil remediation field [1–6], promise
a new alternative in the metal extraction from ores.
In effect, an electrokinetic process is an in situ
technique which combines the principle of elec-
trodialysis with electromigration of ions in the
solid. It is also called either electrodialysis or
electroosmosis.
This fact has induced us to test it for the treat-
ment of Algerian copper ore in both ammonia and
acidic mediums. In this study, electroleaching
experiments with membranes similar to electro-
dialysis have been carried out using typical
samples of copper ore from Ougarta, a locality in
the South West of Algeria. This ore contains cop-
per (average percentage 6.5%) in various minera-
logical forms where malachite (Cu
2
CO
3
(OH)
2
) is
doi:10.1016/j.desal.2005.08.028