Open Journal of Soil Science, 2013, 3, 23-29
doi:10.4236/ojss.2013.31004 Published Online March 2013 (http://www.scirp.org/journal/ojss)
23
Background Soil Mercury: An Unrecognized Source of
Blood Mercury in Infants?
Pamela F. Heckel
1
, Tim C. Keener
2
, Grace K. LeMasters
1
1
College of Medicine, University of Cincinnati, Cincinnati, USA;
2
College of Engineering and Applied Science, University of Cin-
cinnati, Cincinnati, USA.
Email: Pheckel@cdc.gov
Received December 18
th
, 2012; revised January 9
th
, 2013; accepted January 31
st
, 2013
ABSTRACT
Introduction: During the past four decades, mercury (Hg) research focused on fish consumption has explained less
than 22% of Hg in human blood. One overlooked exposure pathway for infants and young children is the concentration
of Hg in soils. Although 75% of the U.S. population lives in urban areas near industrial facilities, minimal data exist
regarding the concentration and speciation of Hg in residential soils. Chronic exposure through ingestion of low
concentrations of Hg in soils may explain a portion of the blood Hg levels noted in infants. Methods: Three relatively
unexposed residential sites in a suburban community were selected. The primary route of contamination was
atmospheric deposition. Soils were digested in a nitric acid-hydrofluoric acid solution and analyzed by cold vapor
atomic absorption spectrophotometry. Measured concentrations of total Hg in local suburban soil samples were
compared to levels measured in a national study of 27 remote and rural sites. The Al-Shahristani pharmacokinetic
model, developed after the 1971 Iraqi Methyl Hg poisoning incident, was used to calculate the blood Hg concentration
in a hypothetical year-old infant. Results: Soil samples contained Hg concentrations ranging from 0.01 to 0.24 ppm
w
.
The distribution of Hg in the soil samples was non-linear and non-normal. The mean soil Hg concentrations at the three
locations were 0.08, 0.05 and 0.08 ppm. Calculated blood Hg concentrations for a 10 kg, year-old infant due to
ingestion of soil (200 mg/day) containing 0.2, 0.4 and 0.8 ppm Hg were 0.08, 0.17 and 0.26 μg/L, respectively. Con-
clusions: The pilot study data appear to support the hypothesis that chronic, low-level soil ingestion may be a signifi-
cant source of Hg for infants. Further study is warranted.
Keywords: Mercury; Blood Mercury; Pharmacokinetics; Air Toxics
1. Introduction
Mercury (Hg) is a known potent toxicant and is found in
the blood, brain and kidney tissues [1]. Organic methyl
mercury (CH
3
Hg) is associated with fish consumption,
whereas inorganic Hg corresponds to exposure from
dental amalgams and other sources of Hg vapor [2].
Elemental mercury (Hg
0
) crosses the placenta and con-
centrates in the fetus [3]. There have also been several
publications that summarized past research into the
speciation of Hg and related biomarkers [4-7].
Decades of research indicate that the developing infant
brain is highly susceptible to damage from neurotoxin-
cants such as Hg [8]. Research over the past 30 years has
confirmed the presence of Hg in fish. Although a statis-
tical analysis indicates a link between fish consumption
and Hg concentrations in infant cord blood, the correla-
tion is weak. Nevertheless, the United States Environ-
mental Protection Agency (USEPA) issued fish con-
sumption advisories for pregnant women [1]. Weekly
records of dietary intake of fish by women during their
pregnancy in Poland explained only 22% of the variabil-
ity of Hg in umbilical cord blood [9]. A weak dose-re-
sponse relationship (r
2
= 0.21) between fish consumption
and infant cord blood Hg was confirmed in another study
of pregnancies among women living along the St. Law-
rence River who ate an average of 3.5 fish meals/month
[10]. Thus, in both studies, fish consumption explained
22% or less of the Hg in cord blood. Hundreds of studies
have examined the possible Hg contribution from foods,
but none of the exposures correlated above 22% with
blood concentrations. Therefore, other routes of exposure
need to be considered.
According to the 2000 census, more than 75% of the
United States population lives in urban areas [11]. Our
pilot study determined the concentration of Hg in topsoil
in the suburbs of an industrialized metropolis. We sug-
gest that there may be a link between Hg in soil and Hg
in infant blood due to increased hand-to-mouth behaviors
during the first two years of life, based in part to a similar
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