Effect of Surface Modification on Strain Rate Sensitivity of
Polypropylene/Muscovite Layered Silicate Composites
Mohd Firdaus Omar
1*
, Nur Suhaili Abd Wahab
1
, Hazizan Md Akil
2,3
,
Zainal Arifin Ahmad
2
, Mohd Fadli Ahmad Rasyid
2
, N.Z. Noriman
1
1
School of Materials Engineering, Universiti Malaysia Perlis, Kompleks Pengajian Jejawi 2, 02600
Arau, Perlis
2
School of Material and Mineral Resource Engineering, Universiti Sains Malaysia,
14300 Nibong Tebal, Pulau Pinang, Malaysia.
3
Cluster of Polymer Composites (CPCs), Universiti Sains Malaysia,
14300 Nibong Tebal, Pulau Pinang, Malaysia.
Corresponding author: firdausomar@unimap.edu.my (Mohd Firdaus Bin Omar)
+0604-9797933 (phone number)
006-9798178 (fax number)
Key words: Ion exchange treatment; Strain rate sensitivity; Muscovite particles; Split Hopkinson
pressure bar apparatus; Strain rates
ABSTRACT
Surface modification is one of the treatment methods that can be implemented to improve
the strain rate sensitivity of composite materials. In this study, both untreated and treated
polypropylene/muscovite layered silicate composites were tested under static and dynamic loading
up to 1100 s
-1
using the universal testing machine and the split Hopkinson pressure bar apparatus,
respectively. Muscovite particles were treated with lithium nitrate and cetyltrimethylammonium
bromide as a surfactant through ion exchange treatment. Results show that the treated
polypropylene/muscovite specimens with fine state of dispersion level shows better rate of
sensitivity as compared to untreated polypropylene/muscovite specimens under a wide range of
strain rate investigated. Apart from that, the rate of sensitivity of both tested
polypropylene/muscovite layered silicate composites also show great dependency on the strain rate
sensitivity was steadily increased with increasing strain rate. Unfortunately, the thermal activation
values show contrary trend.
Introduction
Layered silicates have been widely used as reinforcement materials or filler in the polymer
composite because of their abundance, high strength, larges interfaces and achieving considerable
reinforcement at very small filler loading. Among many different types of layered silicate,
muscovite has become the most promising reinforcement than that of others conventional layered
silicate with similar nature. This was due to its well-defined crystal structure, molecularly smooth
surface, outstanding corona resistance, high aspect ratio and available in large amounts with
relatively low cost
1
. For muscovite layered silicate composites, the factors that need to be
Materials Science Forum Vol. 803 (2015) pp 343-347
© (2015) Trans Tech Publications, Switzerland
doi:10.4028/www.scientific.net/MSF.803.343
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