Research Article
An Investigation into the Impact of Reaction Temperature on
Various Parameters during Torrefaction of Sugarcane Bagasse
Relevant to Gasification
Anthony Anukam,
1,2
Sampson Mamphweli,
1
Prashant Reddy,
3
Omobola Okoh,
2
and Edson Meyer
1
1
Fort Hare Institute of Technology, University of Fort Hare, Private Bag X1314, Alice 5700, South Africa
2
Department of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South Africa
3
Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000, South Africa
Correspondence should be addressed to Anthony Anukam; aanukam@uf.ac.za
Received 14 September 2015; Accepted 25 November 2015
Academic Editor: Mohsen Farahat
Copyright © 2015 Anthony Anukam et al. Tis is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
Torrefaction of sugarcane bagasse was conducted in an electric mufe furnace at 200, 250, and 300
∘
C in order to establish the
impact of heat treatment temperature on various parameters and as a method to improve sugarcane bagasse characteristics for
the purpose of gasifcation. Te results show that weight loss of bagasse reduced as temperature of torrefaction increased due to
excessive devolatilization. A reduced moisture and volatile matter content as well as improved calorifc value were also achieved with
increasing temperature of torrefaction. Te torrefaction progress was again followed by elemental analysis of the material which
showed the presence of C, H, and O in varying proportions depending on torrefaction temperature. Te decrease in the weight
percentages of O
2
and H
2
as torrefaction reaction temperature increased resulted in the accumulation of C in the solid product.
Te thermogravimetric analysis conducted established the maximum reactivity temperature of the torrefed material and revealed
that the degradation of torrefed sugarcane bagasse was accelerated by thermal treatment of the material prior to analysis. Finally,
the study established that torrefaction at 300
∘
C led to a much more degraded material compared to the lower torrefaction reaction
temperatures of 200 and 250
∘
C, respectively.
1. Introduction
Te efect of the application of fossil fuels for energy pro-
duction on global environment has renewed the interest in
the use of alternative energy sources because fossil fuels
contain carbon that has been out of the carbon cycle for
a long time, and therefore their combustion disturbs the
carbon in the atmosphere. Biomass happens to be the only
renewable source of carbon, a chemical element essential
for the manufacture of chemicals and materials. Tere are
two major routes to bioenergy production, which are ther-
mochemical (combustion, gasifcation, and pyrolysis) and
biological (anaerobic digestion and fermentation) processes.
Tese processes can provide a near-term solution to the
problem of energy [1, 2]. However, the low-quality properties
of biomass are ofen revealed when a direct comparison is
made with coal which is still the dominant solid fuel in heat
and electricity generation in South Africa. Te use of raw
biomass for energy production on a commercial scale has
seriously been challenged by high cost of biomass storage,
susceptibility to microbial degradation due to its hygroscopic
nature, heterogeneous nature, and appreciable amount of O
2
relative to C that makes it thermally unstable and produces
reasonable quantities of tar that can be problematic in con-
ventional thermal conversion systems such as the gasifcation
systems [3, 4]. Other issues include its low energy and bulk
densities as well as its high moisture content, which requires
drying before conversion including the high concentrations
of alkali and alkaline earth metal elements. Tese features
result in many issues such as the high energy required for
Hindawi Publishing Corporation
Journal of Chemistry
Volume 2015, Article ID 235163, 12 pages
http://dx.doi.org/10.1155/2015/235163