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Acknowledgements We thank D. Wayne for mass spectrometry measurements of the B content of
our samples, A. Presz for SEM images and S. Gierlotka for help in sample analysis. This work was
supported by the Russian Foundation for Basic Research and by the Strongly Correlated Electrons
Program of the Department of Physical Sciences, Russian Academy of Sciences. Work at Los
Alamos was performed under the auspices of the US DOE.
Authors’ contributions Boron-doped diamond samples were synthesized by E.A.E., and their
physical properties measured by V.A.S., E.D.B., N.N.M., N.J.C., J.D.T. and S.M.S.
Competing interests statement The authors declare that they have no competing financial
interests.
Correspondence and requests for materials should be addressed to V.A.S.
(sidorov@hppi.troitsk.ru)
..............................................................
Intermediate-depth earthquake
faulting by dehydration
embrittlement with
negative volume change
Haemyeong Jung
1
, Harry W. Green II
1,2
& Larissa F. Dobrzhinetskaya
2
1
Institute of Geophysics and Planetary Physics,
2
Department of Earth Sciences,
University of California, Riverside, California 92521, USA
.............................................................................................................................................................................
Earthquakes are observed to occur in subduction zones to depths
of approximately 680 km, even though unassisted brittle failure is
inhibited at depths greater than about 50 km, owing to the high
pressures and temperatures
1–3
. It is thought that such earth-
quakes (particularly those at intermediate depths of 50–300 km)
may instead be triggered by embrittlement accompanying dehy-
dration of hydrous minerals, principally serpentine
1–3
. A problem
with failure by serpentine dehydration is that the volume change
accompanying dehydration becomes negative at pressures of
2–4 GPa (60–120 km depth), above which brittle fracture mecha-
nics predicts that the instability should be quenched
4,5
. Here we
show that dehydration of antigorite serpentinite under stress
results in faults delineated by ultrafine-grained solid reaction
products formed during dehydration. This phenomenon was
observed under all conditions tested (pressures of 1–6 GPa;
temperatures of 650–820 8C), independent of the sign of the
volume change of reaction. Although this result contradicts
expectations from fracture mechanics, it can be explained by
separation of fluid from solid residue before and during faulting,
a hypothesis supported by our observations. These observations
confirm that dehydration embrittlement is a viable mechanism
for nucleating earthquakes independent of depth, as long as
there are hydrous minerals breaking down under a differential
stress.
A popular hypothesis for overcoming brittle fracture inhibition,
especially for earthquakes at intermediate depths (,300 km), is
assistance of brittle fracture by generation of a free fluid as a result of
dehydration of serpentine or other hydrous minerals
1–3,6–11
. The
phenomenon of dehydration embrittlement was discovered
almost 40 years ago
1
but has been studied only sporadically since
that time
4–8
. In particular, this phenomenon has not been addressed
by controlled deformation experiments at pressures greater than
700 MPa, equivalent to only ,20 km depth in Earth. Studies of
acoustic emission at elevated pressures
5,8
, however, have impli-
cations for deeper earthquakes. The latter studies, although lacking
control of differential stress, strain, or strain rate, recorded acoustic
emissions at much higher pressures and inferred that faulting had
occurred.
The fracture mechanics explanation of how dehydration
embrittlement can enable brittle shear failure at elevated pressure
is based upon production of a pore pressure as a consequence of a
positive volume change, DV , of the dehydration reaction and
consequent decrease in the effective pressure on existing or potential
planes of weakness. Thus, as conventionally understood, the theory
predicts that if the DV of the reaction were to become negative,
failure would become more difficult and the shearing instability
would vanish
4,5
. Because hydrous fluid is much more compressible
than solid silicates, the total DV of dehydration of the common
hydrous phases of primary interest (for example, serpentine and
chlorite) is progressively reduced as pressure increases and becomes
negative at pressures of 2–4 GPa, equivalent to pressures of
60–120 km in Earth. One consequence of this prediction is that
earthquakes should not be possible by dehydration embrittlement at
greater depths
5
. However, dehydration embrittlement is the only
earthquake nucleation mechanism known to be viable for depths
less than 300 km (ref. 2). Thus, it is important to determine whether
this mechanism can function under conditions where DV is
negative.
We report here the results of deformation experiments at press-
ures of 1–6 GPa and temperatures of 550–820 8C using an antigorite
serpentinite from Val Malenco, Italy, for which the phase diagram
has been measured
12
. Figure 1a shows the experimental conditions
investigated; the slope of the high-temperature limit of antigorite
stability (Fig. 1a) is negative above ,2.2 GPa, reflecting negative DV
of reaction above that pressure.
Figure 1b–f shows microstructures of the starting material and
results of annealing without deformation outside antigorite sta-
bility. The layering, strong foliation and proportions of antigorite
and relict olivine shown are typical of our starting material. Figure 1f
shows breakdown of antigorite along boundaries with relict olivine
and healed cracks of several orientations outlined by fluid
inclusions; such inclusion trails are rare in the starting material,
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