Vol. 186, No. 3, 1992
August 14, 1992
BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS
Pages 1546-1552
SOLUBILIZATION OF RIBOSOMES IN REVERSE MICELLES
Giordano Palazzo ° and Pier Luigi Luisi*
°Dipartimento di Chimica, Universita" di Bari
* Institut fiir Polymere der ETH-Ziirich, Switzerland
Received June i0, 1992
Summary: Pig liver ribosomes have been solubilized in reverse micelles
constituted by bis (2-ethyl hexyl) sodium sulfosuccinate (AOT) in
isooctane and 3.6% water, v:v. The micellar ribosomal solutions are
transparent, show no significant scattering and permit direct
spectroscopic observation of the ribosomes to be made. Ultraviolet
absorption and circular dichroic spectra have been recorded and indicate
that the ribosomes maintain in the micellar environment their structural
integrity. Some possible applications of these micellar systems are
discussed. ® 1992 Academic Press, Inc.
Enzymes solubilized in reverse micelles have attracted the
attention of a number of investigators over the last ten years. Enzymes
are thought to be hosted in the water pool of the reverse micelles, and
protected from the apolar solvent by a layer of water and surfactant
molecules. The very large number of papers dealing with enzymes and
proteins in reverse micelles reflects on the one hand the biotechnological
expectations, and on the other the fascination for this type of
biochemistry with a regulable enzyme microreactor (for reviews see Ref
1-3).
One would think that nucleic acids in reverse micelles would have
enjoyed similar popularity. It is not so, and actually there are only very
few papers dealing with this subject (4-6). The preliminary results were
however interesting: for example, it could be shown that high molecular
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Copyright © 1992 by Academic Press, Inc.
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