Materials Sciences and Applications, 2012, 3, 587-595 http://dx.doi.org/10.4236/msa.2012.39084 Published Online September 2012 (http://www.SciRP.org/journal/msa) 587 Effect of Radial Expansion of Cr-Mo Steel Tubes on Their Corrosion Behavior in Sea Water A. C. Seibi 1* , P. Rostron 2 , A. Elramady 1 , B. Mishra 3 , O. Al Nazer 1 , S. Al Ameri 1 1 Mechanical Engineering Department, Petroleum Institute, Abu Dhabi, UAE; 2 Chemistry Department, Petroleum Institute, Abu Dhabi, UAE; 3 Metallurgical & Materials Engineering Department, Colorado School of Mines, Golden, USA. Email: * aseibi@pi.ac.ae Received March 22 nd , 2012; revised May 7 th , 2012; accepted June 19 th , 2012 ABSTRACT This paper studies the effect of expansion ratio on the corrosion rate of the expanded tubes exposed to sea water as well as the microstructure changes caused by the expansion of Cr-Mo steel tubes to large permanent deformations. 2.25 Cr-1.0 Mo steel (schedule 40 and schedule 80) tubes were subjected to various expansion ratios of 10%, 15%, 20%, and 25% by pushing conical mandrels through them using a piston. The microstructure was also studied to determine the effect of the expansion on the grain structure of the material. Microscopic examination of the expanded tubes revealed that grains elongate along the direction of the hoop stress and this elongation increases with an increase of expansion ratio. Moreover, it was found that corrosion rate and hardness increase with an increase in expansion ratio. Keywords: Expanded Tubes; Corrosion in Seawater; Potentiostat; Hardness; Enlarged Grain Size 1. Introduction Downhole tubular expansion of pipes (casings) is becom- ing a normal practice in the petroleum industry to repair damaged casings, shutdown perforations, and ultimately achieve mono-diameter wells. Tubular expansion is a cold drawing metal forming process, which consists of running conical mandrels through casings either mechanically us- ing a piston or hydraulically by applying a back pressure. This mechanism subjects the pipes to large radial plastic deformations up to 30% of the inner diameter. Extensive literature related to the viability and advantages of this technology in the field is summarized [1]. Experimental and numerical studies were carried out in the past two decades to understand the mechanical behavior of expanded tubes/pipes. However, a limited number of research work related to the corrosion behavior of plastically deformed materials is available in the literature. The effect of the degree of corrosion on the mechanical properties of steel under plastic deformation was reported to be critical [2]. The study revealed that the hardness of 8 mm bars BSt500 s steel reduced by 25% - 35% and 2% - 10% in the outer and inner layers, which is due to removal of the marten- site layer in the outer layer [3]. Moreover, it was found that the increase in the degree of plastic deformation aids the anodic and cathodic reactions between a steel boiler and the acid solution that was used for flushing [4]. The present paper, therefore, studies the effect of expansion ratio on the corrosion rate of 2.25 Cr-1.0 Mo steel sam- ples exposed to aerated sea water as well as the hardness and microstructure changes of expanded tubes. 2. Theoretical Background 2.1. Stress Analysis The mechanical response of tubes subjected to radial ex- pansion was studied [5] by considering the equilibrium conditions of an infinitesimal element (see Figure 1) from which an expression for the hoop stress was deduced: 2 3 2 2 2 1 3 1 max 2 2 1 2 2 2 1 3 1 1 cos cos cos h m r h h h r q t r r h h h r r (1) where q m represents the contact pressure between the man- drel and tube surface and is given by 2 2 2 1 (1 cot ) π (1 cot ) c m m F p q r r (2) The terms F c , p m , μ denote respectively the expansion force, contact pressure, and friction coefficient. Equation (1) expresses the stress in terms of the contact pressure, * Corresponding author. Copyright © 2012 SciRes. MSA