JOURNAL OF MATERIALS SCIENCE LETTERS 12 (1993) 218-219
Fibre-matrix interface transverse tensile debonding
P. MARSHALL, N. STONE
British Aerospace plc, Sowerby Research Centre, PO Box 5, Filton, Bristol BS12 7QW, UK
The strength of the bond between the reinforcing
fibre and matrix in composite materials is recognized
to be of great importance to the bulk properties of
the laminated composite. Many techniques have
been devised to assess the properties of the fibre-
matrix interface and some have used laminated
materials, either testing to destruction in three-point
bending [1] or by non-destructive monitoring of the
viscoelastic behaviour of the laminate [2].
However, these techniques do not measure prop-
erties exclusive to the fibre-matrix interface. There
are single-fibre tests which unambiguously measure
the fibre-matrix interface bond, for example the
push-out test [3], fibre fragmentation [4] and pull-
out test [5]. One limitation of these methods is that
the fibre is loaded axially so that only the interface
shear properties can be evaluated. Although the
shear properties of the interface are important, it is
also desirable to know the interface tensile strength.
The geometrical constraints to developing a trans-
verse tensile mechanical test applicable to small-
diameter reinforcing fibres are clear. Some success
has been achieved with a compression specimen
consisting of an hourglass-shaped resin sample with
a centrally located fibre. Under compression the
Poisson ratio effects concentrate a normal tensile
force perpendicular to the fibre axis. In reflected
light interface debonding can be detected and the
interface tensile strength calculated [4]. Unfortun-
ately, the technique is not easily applied to carbon
fibres.
We designed and tested a method for measuring
the transverse tensile fibre-matrix bond strength of
carbon fibres. The method exploits the conductive
properties of the fibres and electromagnetic forces
that can be induced when electrical current is
applied.
Polyacrylonitrile (PAN)-based intermediate-
modulus carbon fibres of diameter 5/xm were
mounted into card "window frames" with alumi-
nium tape and carbon-filled adhesive providing
electrical contact to the fibres (Fig. 1). Two samples
of this type were placed together with a 70/zm-thick
film of the thermoplastic polyetherimide (PEI)
between them. A potential of 40 V was applied in
parallel across the two fibres for approximately 10 s.
The current flowing in the same direction along each
fibre induced an attractive electromagnetic force
between the fibres, forcing them towards each other
and into contact with the PEI film (Fig. 2a). Resis-
tive heating of the fibres caused the PEI surface to
melt. Upon removing the current the PEI cooled
rapidly, bonding the fibre into place. The sample
218
~ Aluminium tape
[\\\, ~x{~--~ Car bon fibre
~
Hole in card
..... Fold
Fibre in card window Section through two
card windows
Two fibres separated
by PEI film
Figure 1 Sample preparation.
consisted at this stage of two parallel fibres
embedded in the PEI film (Fig. 2b). The procedure
was conducted under an optical microscope, but the
situation is illustrated better in the electron micro-
graph shown in Fig. 3, where a single side of the
sample can be seen in detail. The tensile force
needed to break the interface bond was provided by
passing a short current pulse in opposite directions
along the two fibres, which generated an instantan-
eous repulsive electromagnetic force (Fig. 2c). A
field-effect transducer ensured a current pulse decay
of <20/xs, which minimized the resistive heating
effects. The power supply output was increased in
steps, providing incremental increases in the electro-
magnetic force until the fibres became debonded.
Fig. 4 shows an electron micrograph of a debonded
fibre; note the thin layer of PEI adhering to the fibre
surface.
The force acting between the fibres at debonding,
F, can be calculated from
F = IxliI21/27ra
0261-8028 © 1993 Chapman & Hall