Supporting Information: Hydroamination of Terminal Alkynes with Secondary Amines Catalyzed by Copper: Regioselective Access to Amines Janet Bahri, a,b Rémi Blieck, a Bassem Jamoussi, b Marc Taillefer* a and Florian Monnier* a a École Nationale Supérieure de Chimie de Montpellier, Institut Charles Gerhardt Montpellier CNRS UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05, France b Laboratoire de Chimie, Institut Supérieur d’Education et de Formation Continue, 43 Rue de la Liberté, 2019, Le Bardo, Tunisia. florian.monnier@enscm.fr ; marc.taillefer@enscm.fr I- General experimental methods S1-S2 II- Typical procedures for the preparation of compounds 3a-3w and 7a-7w: S2-S3 III- Characterization of compounds 7a-7w S4-S38 I. General considerations All reactions were performed in oven-dried 45x14.75 mm Screw tubes under an atmosphere of argon. N-methyl-2-pyrrolidone (NMP) was distilled from P 2 O 5 and stored over activated 3Å molecular sieves under an argon atmosphere. CuCN stored in a dessicator cabinet and S1 Electronic Supplementary Material (ESI) for ChemComm. This journal is © The Royal Society of Chemistry 2015