FEMS Microbiology Letters 17 (1983) 63-67 63
Published by Elsevier Biomedical Press
Recombinant plasmids containing menaquinone biosynthetic
genes of Escherichia coli
Duncan J. Shaw, E. Clare Robinson, R. Meganathan *, Ronald Bentley * and John R. Guest
Department of Microbiologr', University of Sheffield, Sheffield SIO 2TN, U.K., and * Department of Biological Sciences, Universi(v of
Pittsburgh, Pittsburgh, PA 15260, U.S.A.
Received 14 September 1982
Accepted 20 September 1982
1. INTRODUCTION
Menaquinone (ML; Vitamin K2) is an essential
electron carrier in the anaerobic ATP-generating
fumarate reductase system of Escherichia coli [1-3]
and it is also involved in the anaerobic biosynthe-
sis of pyrimidines, porphyrins and succinyl-CoA
[4-6]. Previous studies have identified five mena-
quinone biosynthetic genes (menA, B, C, D, E)
whose roles in the pathway are as follows [7-12]:
menC, D menE
chorismate ~ o-succinylbenzoate ---,
(osB)
menB
o-succinylbenzoyl-coenzyme A --*
(OSB-CoA)
menA
1,4-dihydroxy-2-naphthoate
(DHN)
demethylmenaquinone ~ menaquinone
(DMK) (MK)
The menA gene is located at 88 min in the E.
coli linkage map and the menB, C, D and E genes
are clustered at 48.5 min with the clockwise order
Correspondence to: Prof. John R. Guest, Department of Mi-
crobiology, Sheffield University, Western Bank, Sheffield, S10
2TN, U.K.
menC-E*-B-D [ 12,13]; the asterisk denotes that the
position of menE is not known relative to menC
and menB.
To facilitate studies on the enzymology of
menaquinone biosynthesis and on their organisa-
tion and expression, the men genes have been
cloned. The isolation and properties of a recombi-
nant lambda transducing phage containing the
menB, C and E genes, but only part of the menD
gene, have been reported previously [12,14]. This
paper describes the isolation of two ColEl-men +
hybrid plasmids, one of which contains the entire
menD gene. Also described is the alignment of the
genetic and restriction site maps of the men region
and the amplification of menaquinone biosyn-
thetic enzyme activities in plasmid-carrying strains.
2. MATERIALS AND METHODS
2.1. Bacteria, phage and plasmids
Strains of E. coli K-12 used for genetic testing,
isolation of recombinant plasmids, and phage
propagation are shown in Table 1. A mixture rep-
resenting all the colonies of the Clarke-Carbon
ColE1-E. coli gene bank [15] was kindly provided
by Dr. S.T. Cole. The XmenCE*B(D) transducing
phage (XG68) carrying the menB, C and E but
only part of D genes has been described previously
[12,14].
0378-1097/83/0000-0000/$03.00 © 1983 Federation of European Microbiological Societies
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