Research Article
Numerical Simulation of Galvanic Corrosion between Carbon
Steel and Low Alloy Steel in a Bolted Joint
Rachid Radouani, Younes Echcharqy, and Mohamed Essahli
Laboratory of Applied Chemistry and Environment, Faculty of Science and Technology, University of Hassan 1, Settat, Morocco
Correspondence should be addressed to Rachid Radouani; r.radouani@gmail.com
Received 10 August 2017; Revised 20 November 2017; Accepted 28 November 2017; Published 27 December 2017
Academic Editor: Jerzy A. Szpunar
Copyright © 2017 Rachid Radouani et al. Tis is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
Te galvanic corrosion of a bolt joint combining carbon steel end plate and low alloy steel bolt was investigated electrochemically in a
1 M HCl solution. Te corrosion parameters of the joint components were used for numerical simulation using Comsol Multiphysics
sofware to analyze the galvanic corrosion behavior at the contact zone between the head bolt and the end plate. In this research work
we evaluate the variation of the corrosion rate in the steel end plate considered as the anode, in order to determine the lifetime of the
bolted assembly used in steel structures. Tree materials (20MnCr5, 42CrMo4, and 32CrMoV13) and three bolts (M12, M16, and
M20) were tested in two thicknesses of electrolyte 1 M HCl ( = 1 mm, = 20 mm). It is found that the corrosion rate of the anode
part (end plate) is higher for 32CrMoV13 materials and it increases if both diameter of the bolt and thickness of the electrolyte
increase (Cr(M20) > Cr(M16) > Cr(M12) and Cr( = 20 mm) > Cr( = 1 mm)). Tis corrosion rate is higher in the contact area
between the bolt head and the end plate, and it decreases if we move away from this contact area.
1. Introduction
Galvanic corrosion can simply be defned as the corrosion
that occurs as a result of one metal being in contact with
another in a conducting, corrosive environment. Te cor-
rosion is stimulated by the potential diference that exists
between the two metals: the more noble material acting as
a cathode where some oxidizing species is reduced and the
more active metal, which corrodes, acting as the anode. Te
anodic reaction is, by defnition, some form of metal disso-
lution; the cathodic reaction is, in the majority of practical
situations, either oxygen reduction or hydrogen evolution,
or a combination of both. Many factors afecting galvanic
corrosion are already discussed to determining whether or
not galvanic corrosion will occur in a particular instance and
if so at what rate; it is important when considering the theory
of galvanic corrosion to be aware of these factors including
electrode potential, reaction kinetics, alloy composition,
protection flm characteristics, bulk solution environment,
total geometry, and type of joint [1].
Tere is a high incidence of past scientists taking an
interest in corrosion to understand what causes it and what
limits or accelerates the process. Numerous studies have
been conducted; some take a more global outlook [2],
whereas some take a more focused approach [3]. Te study
conducted in [2] looked at many diferent galvanic couples
commonly used in seawater applications. Te study focused
on developing reasonable models for systems experiencing
varying periods of exposure to the corrosive environment.
Simulation of galvanic corrosion between magnesium
and aluminum has been performed by Lacroix et al. [4],
Deshpande [5–7], Jia et al. [8], and Trinh et al. [9] who have
studied the corrosion of magnesium alloys in contact to mild
steel under static conditions. Te publications of Murer et
al. [10–12] and Shi and Kelly [13] in this context also gave
an extended insight into the topic, especially in the very
important choice of boundary conditions. New studies of Sun
et al. [14], who applied the mathematical approach of Yan et
al. [15] to the modeling of deposit formation under seawater
conditions, clearly introduce a possible way of a useful model
built up for the mentioned purpose. Te following studies
and results are based on the progress achieved by them. Basic
galvanic current density computations were modifed by layer
growth aspects leading to time dependent variations in the
electrochemical response of the electrodes.
Hindawi
International Journal of Corrosion
Volume 2017, Article ID 6174904, 10 pages
https://doi.org/10.1155/2017/6174904