Abstract
UV-Vis technique is a compulsory technique for the optical study of
the materials. Optical study helps the researcher for the application
s of nanomaterials for different uses. Different devices are fabricat-
ed on the basis of optical properties of the materials especially solar
cells. With the help of this technique optical band gap can be calcu-
lated which helps to choose the materials for the energy conversion
purpose like light energy to electrical energy in solar cell. Also, from
this technique purity of the sample can be measured by comparison
with the reference solution. Here results of different materials are
described which can help to better understand the analysis of Uv-
Vis spectroscopy results.
Keywords
UV-VIS; Band gap; Nanoparticles
Abbas, J Nanomater Mol Nanotechnol 2019, 8:3
DOI: 10.4172/2324-8777.1000268
Journal of Nanomaterials &
Molecular Nanotechnology
Understanding the UV-Vis
Spectroscopy for Nanoparticles
Qaisar Abbas*
Introduction
Ultra violet and visible (Uv-Vis) absorption spectroscopy is the
technique by which we measure attenuation of light which passes
through a under consideration sample or also after reflection from the
sample. Both parts (Uv and Vis) of light are energetic that can excite
electrons to higher energy levels [1].
Short Communication
Principle of the Uv-Vis spectroscopy
This follows the principle of the Beer lambert law which states that
absorption of the light by the sample is directly proportional to the
path length and concentration of the sample [2].
Mathematically,
A=log (I0/I)=Ecl
Where, A=absorbance
I0=intensity of light incident upon sample cell
I=intensity of light leaving sample cell
C=molar concentration of solute
L=length of sample cell (cm.)
E=molar absorptivity
Range
Data provided in the given below Table 1.
Explanation of the working
When light falls on the sample each material absorbs a specific
range of the light and shows the behavior accordingly. Electron from
the atom excites towards the higher state from the lower energy state.
These two states are classified in two types LUMO and HOMO.
1. LUMO : Lowest unoccupied molecular orbit
2. HOMO: Highest occupied molecular orbit.
There are further classification of bonds and these bonds form
according to the specific behavior of the sample which is being
analyzed under the light. The details are shown in Figures 1 and 2.
Sigma is stronger bond while pi is weak bond and it depends on
the material which bond formed. The bond formation of organic
materials is shown in Figure 3.
Applications of the Uv-Vis spectroscopy
The most important factor of the technique is its application for
the researcher to give the information about the material when light
falls on it.
Detection of Chromophore functional group: To determine the
functional group in the material exclusively it confirms the presence
and absence of the Chromosphere in the sample which should be
compound. Chromophore is an atom or group which is responsible
of the color of the compound.
Determine the unknown compound: With the help of the Uv-Vis
spectroscopy unknown compound can be determined in the sample.
For this purpose, required compound is compared to spectrum of
the reference compound if luckily both the spectrum is matched then
confirmation of unknown compound can be noted.
Purity of the sample: The purity of the substance can be measured
by this unique technique for this purpose absorption of the reference
and the sample under observation is compared and via relative
calculations of the absorption intensity purity of the sample can be
confirmed.
Band gap calculations: An interesting application of this
technique is the calculations of the band via different method there
are different software’s are available for this purpose.
Mathematically:
E=hc/λ (1)
E=energy band gap
h=planks constant, c=speed of light
λ=wavelength
*Corresponding author: Qaisar Abbas, Department of Physics,
COMSATS University Islamabad, Lahore Campus 54000, Pakistan, E-mail:
qaisar022@gmail.com
Received: March 05, 2019 Accepted: May 16, 2019 Published: May 31, 2019
Table 1: Ranges of wavelength.
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Light Wavelength range in nm
Ultraviolet 200-400
Visible 400-800