A Correlation for Phase Behavior of Nonionic Surfactants
M. BOURREL, 1 J. L. SALAGER, 2 R. S. SCHECHTER, AND W. H. WADE
Departments of Chemistry and Petroleum Engineering, University of Texas at Austin,
Austin, Texas 78712
Received November 20, 1979; accepted January 30, 1980
In previous studies, the s ystematics of variation of phase behavior of oil/water/surfactant systems
have been detailed for anionic surfactants. The present study details the behavior of such systems
with nonionic surfactants, including the variables: temperature, alcohol type and concentration,
added electrolyte, ethylene oxide number of the surfactant, alkane molecular weight for the oil
phase, and the hydrophobic molecular weight for the surfactant.
INTRODUCTION
Waterflooding is a standard technique for
improving the efficiency of oil recovery
from a reservoir; yet, half the oil remains
thermodynamically trapped as dispersed
droplets. If the interfacial tension between
oil and water can be reduced sufficiently,
then additional oil droplets may be dis-
placed (1). Surfactant solutions have been
formulated to attain these required ultralow
interfacial tensions (2). Furthermore, it has
been shown that these tensions are often ob-
served for conditions such that the oil/water/
surfactant mixtures separate into three
distinct phases (3), and recent studies (4, 5)
have documented the equivalency of these
two approaches.
When three-phase systems form, the sur-
factant is located largely in the phase of
density intermediate between that of water
and oil and hence is called the middle
phase. Winsor (6) called such systems with
the thermodynamically stable middle-phase
microemulsion in equilibrium with both
excess oil and water phases Type III.
1 Present address: Societe Nationale Elf Aquitaine,
Lacq, France.
2 Present address: Universidad de los Andes,
Merida, Venezuela.
Type I systems are those for which the
surfactant is in the aqueous phase (micro-
emulsion in equilibrium with excess oil) and
Type II systems consist of microemulsion
(surfactant in oil) in equilibrium with excess
water. Of course, in each system residual
surfactant exists in all the various equi-
librium phases.
It is possible to effect a I~III~II
transition (or the reverse) by changing any
one of a number of system variables. For
the case of anionic surfactants, extensive
studies of this transition have been con-
ducted and a correlation between the
salinity, oil, water/oil ratio, alcohol type and
concentration, surfactant structure, and
temperature has been established (5). All
of these parameters change the relative
affinity of the surfactant for the oil and
water and therefore tend to influence the
system type. The correlation shows that the
system is particularly sensitive to the
salinity and often a small increase of this
parameter can promote the I ~ III ~ II
transition. Temperature, on the other hand,
does not strongly influence anionic sur-
factant partitioning (5). A similar quantita-
tive study of nonionic phase behavior has
not yet been reported. However, a first
qualitative study of the effect of some of
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Journal of Colloid and Interface Science, Vol. 75, No. 2, June 1980
0021-9797/80/060451-11502.00/0
Copyright© 1980 by Academic Press,Inc.
All rightsof reproduction in any formreserved.