-Cell Calcium-Independent Group VIA Phospholipase A 2 (iPLA 2 ) Tracking iPLA 2 Movements in Response to Stimulation With Insulin Secretagogues in INS-1 Cells Shunzhong Bao, 1 Chun Jin, 1 Sheng Zhang, 1 John Turk, 1 Zhongmin Ma, 2 and Sasanka Ramanadham 1 Evidence that group VIA cytosolic calcium-independent phospholipase A 2 (iPLA 2 ) participates in -cell signal transduction includes the observations that inhibition of iPLA 2 with the bromoenol lactone suicide substrate suppresses glucose-stimulated insulin secretion and that overexpression of iPLA 2 amplifies insulin secre- tory responses in INS-1 insulinoma cells. Immunofluo- rescence analyses also reveal that iPLA 2 accumulates in the perinuclear region of INS-1 cells stimulated with glucose and forskolin. To characterize this phenomenon further, iPLA 2 was expressed as a fusion protein with enhanced green fluorescent protein (EGFP) in INS-1 cells so that movements of iPLA 2 are reflected by changes in the subcellular distribution of green fluores- cence. Stimulation of INS-1 cells overexpressing iPLA 2 -EGFP induced greater insulin secretion and punctate accumulation of iPLA 2 -EGFP fluorescence in the perinuclear region. To determine the identity of organelles with which iPLA 2 might associate, colocal- ization of green fluorescence with fluorophores associ- ated with specific trackers targeted to different subcellular organelles was examined. Such analyses reveal association of iPLA 2 -EGFP fluorescence with the ER and Golgi compartments. Arachidonate-contain- ing plasmenylethanolamine phospholipid species are abundant in -cell endoplasmic reticulum (ER) and are excellent substrates for iPLA 2 . Arachidonic acid pro- duced by iPLA 2 -catalyzed hydrolysis of their sub- strates induces release of Ca 2 from ER stores—an event thought to participate in glucose-stimulated insu- lin secretion. Diabetes 53 (Suppl. 1):S186 –S189, 2004 P hospholipase A 2 (PLA 2 ) is a diverse group of enzymes that catalyze hydrolysis of the sn-2 substituent from glycerophospholipid substrates to yield a free fatty acid and a 2-lysophospholipid (1,2). Among the PLA 2 s is an 84-kDa cytosolic PLA 2 that does not require Ca 2 for catalysis and is designated group VIA cytosolic calcium-independent phospholipase A 2 (iPLA 2 ) (3–5). A role for iPLA 2 in signal transduction in insulin- secreting -cells is suggested by the observations that inhibition of iPLA 2 activity with the bromoenol lactone (BEL) suicide substrate of iPLA 2 suppresses insulin secretion, and overexpression of iPLA 2 amplifies glucose- and forskolin-stimulated insulin secretion from pancreatic islets and INS-1 insulinoma cells (6,7). Stimulation of iPLA 2 -overexpressing INS-1 cells with cAMP-elevating agents also induces translocation of iPLA 2 to the perinu- clear region (7). This is of interest because glucose pro- motes both -cell insulin secretion and proliferation, and glucose-induced INS-1 cell mitogenesis is cAMP depen- dent (8). To characterize iPLA 2 subcellular movements further, we developed INS-1 cell lines that overexpress iPLA 2 as a fusion protein with enhanced green fluores- cent protein (EGFP) so that green fluorescence associated with EGFP reflects the location of iPLA 2 . Simultaneous monitoring of florescence associated with various tracking molecules allowed us to identify specific subcellular or- ganelles with which iPLA 2 associates when cells are stimulated. RESEARCH DESIGN AND METHODS Preparation of a construct for expressing iPLA 2 as a fusion protein with EGFP and selection of stably transfected clones. Full-length iPLA 2 cDNA was amplified by PCR using the following primer set: sense, 5 AGCTTCGAATTCATGCAGTTCTTTGGACGC-3, and antisense, 5-TTC GATATCGGGAGATAGCAGCAGCTGG-3. The amplified full-length iPLA 2 from the pMSCV-neo-iPLA 2 constructs were then subcloned into the pEGFP-N2 (Clontech, Palo Alto, CA) after the immediate early promoter of cytomegalovirus major and before EGFP coding sequences in the same code-reading frame with EGFP. The EGFP-N2 control vector and the con- struct encoding iPLA 2 -EGFP (FPN2) fusion protein were transfected into INS-1 cells with a Gene PORTER transfection system according to the manufacture’s instructions (Gene Therapy Systems, San Diego, CA). Stably transfected clones were selected using G418 (0.4 mg/ml). Stably transfected cells obtained with EGFP-N2 control vector and FPN2 construct are designed as N2 cells and FPN2 cells, respectively. From 1 Mass Spectrometry Resource, Division of Endocrinology, Diabetes, and Metabolism, Department of Medicine, Washington University School of Med- icine, St. Louis, Missouri; and the 2 Division of Experimental Diabetes and Aging, Mount Sinai School of Medicine, New York, New York. Address correspondence and reprint requests to Sasanka Ramanadham, Washington University School of Medicine, Department of Medicine, Box 8127, 660 S. Euclid Ave., St. Louis, MO 63110. E-mail: sramanad@im.wustl.edu. Received for publication 14 March 2003 and accepted in revised form 7 May 2003. This article is based on a presentation at a symposium. The symposium and the publication of this article were made possible by an unrestricted educa- tional grant from Les Laboratoires Servier. BEL, bromoenol lactone; EGFP, enhanced green fluorescent protein; FITC, fluorescein isothiocyanate; iPLA 2 , group VIA cytosolic calcium-independent phospholipase A 2 ; PLA 2 , phospholipase A 2 . © 2004 by the American Diabetes Association. S186 DIABETES, VOL. 53, SUPPLEMENT 1, FEBRUARY 2004