S1
SUPPORTING INFORMATION
Cu(I), Co(II) and Fe(II) coordination polymers with
pyrazine and benzoate as ligands. Spin crossover,
spin canting and metamagnetism phenomena
Pilar Amo-Ochoa,
a,*
Oscar Castillo,
b,*
Félix Zamora
a
a
Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid (Spain);
b
Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País
Vasco (UPV/EHU), Apartado 644, E–48080 Bilbao (Spain).
Contents:
Figures S1-S3. Supramolecular crystal buildings of compounds 1-4.
Tables S1-S2. Selected bond lengths and angles (Å,º) of compounds 1-4.
Figures S4-S5. Thermogravimetric curves under synthetic air atmosphere of compounds 3-4.
Figure S6. Field cooling (FC) and zero-field cooling (ZFC) magnetization curves for compound 3
under an applied magnetic field of 100 Oe.
Description of the experimental procedure to obtain [Cu
II
2
(Bz)
4
(pyz)]
n
complex.
Electronic Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2013