Nonlinear Rayleigh waves in a medium with a monatomic nonlinear coating A. S. Kovalev* and E. S. Sokolova B. Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, pr. Lenina, 47, 61103Khar’kov, Ukraine A. P. Mayer Institut fu ¨r Theoretische Physik, Universita ¨t Regensburg, D-93040, Regensburg, Germany G. A. Maugin Laboratoire de Mode ´lisation en Me `canique, Universite ´ Pierre et Marie Curie, 75252, Paris, France Submitted March 3, 2003 Fiz. Nizk. Temp. 29, 530–538 May 2003 The nonlinear dynamics of surface acoustic waves at the surface of a linear elastic half-space coated with a monolayer of a nonlinear material is investigated. A one-dimensional nonlinear integrodifferential equation describing the dynamics of such a system is derived. The model proposed is used to study Rayleigh solitons with a stationary profile. The possible phenomenological generalizations of the equations derived and their exact soliton solutions are discussed. © 2003 American Institute of Physics. DOI: 10.1063/1.1542503 The theory of nonlinear acoustic waves in one- dimensional atomic chains has been developed in detail. 1,2 The problem of nonlinear acoustic surface waves at the sur- face of an anharmonic half-space is much more complicated because it is two-dimensional. 3–12 However, this problem be- came especially topical immediately after a series of experi- ments were performed on the propagation of nonlinear sur- face waves 13,14 and high-intensity acoustic surface pulses. 15–17 Most experiments were performed on samples consisting of a substrate coated with a film of a different material. The presence of a film coating is very important because it results in the appearance of an additional strong dispersion of linear waves and the competition between this dispersion and the nonlinearity gives rise to stationary non- linear surface waves and surface solitons with a stationary profile. The analytic study of these nonlinear waves simpli- fies somewhat when the substrate can be treated in the linear approximation. 18 The two-dimensional problem for the sub- strate can be solved exactly. It is important to underscore that such a formulation of the problem a linear half-space with a nonlinear coatingis fully realizable experimentally. For ex- ample, in Ref. 19 experimental data are presented for anhar- monic surface phonon effects in systems with a metallic sub- strate coated with a monolayer of inert-gas atoms Ar or Xe. A similar situation arises for an inert-gas monolayer on a graphite surface. 1. FORMULATION OF THE MODEL We shall consider the propagation of a nonlinear surface acoustic wave in the X direction along the surface of the half-space Z 0 coated with a monatomic layer. The dis- placements are independent of the coordinate Y and the problem is effectively two-dimensional.We shall confine our attention to the particular case where the nonlinear inter- action of the atoms in the surface monolayer with one an- other and with atoms of the substrate surface is central. Each atom of the monolayer interacts with its nearest neighbors in the direction of the X axis in the monolayer and with the nearest neighbor and next two neighboring atoms in the sub- strate surface see Fig. 1. Keeping only the first nonlinear terms in the expression for the interaction of the atoms in the surface film with one another and with substrate atoms we obtain the following expression for the total energy of the monatomic coating: E = n M 2 dU n dt 2 + dV n dt 2 + n 2 n , n +1 2 - 3 n , n +1 3 + 2 n 2 - 3 n 3 + 2 n , n +1 2 - 3 n , n +1 3 + 2 n , n -1 2 - 3 n , n -1 3 , 1 where U n and V n are the displacements of the n th atom in the monolayer in the X and Z directions; n , n +1 = U n -U n +1 -a 2 +V n -V n +1 2 -a = ˜ n , n +1 -a is the deviation of the interneighbor distances in the surface film from their values a in equilibrium; M is the mass of an atom in the monolayer; FIG. 1. Geometry of the problem. LOW TEMPERATURE PHYSICS VOLUME 29, NUMBER 5 MAY 2003 394 1063-777X/2003/29(5)/7/$24.00 © 2003 American Institute of Physics