Plasmon Enhanced Light Trapping for Thin Film Silicon Solar Cells
Application
Pushpa Ra j Pudasaini 1* and Arturo A Ayon
MEMS Research Lab, Department of Physics and Astronomy, University of Texas at San Antonio, One
UTSA Circle, San Antonio, Texas, 78249, USA
ABSTRCT -In this paper, the localized surface plasmon effect
of gold (Au) nanoparticles deposited on the silicon nanohole
(SiNH) array textured surface is studied via simulation for better
light trapping purpose for thin flm silicon solar cells application.
The ultimate efciency of the optimized SiNH array textured
surface is increased by 27.5% with the inclusion of Au
nanoparticles on its surface. The highest ultimate efciency of the
proposed geometry herein (39.67 %) is still 12.8% greater than
the single layer antirefection (AR) coating of Si3N4 on SiNH
array textured surface without Au nanoparticles. The forward
scattering of incident radiation by the Au nanoparticles near their
localized plasmon resonance is responsible for the strong feld
enhancement in the substrate and hence the higher ultimate
efciency of the solar cell.
Inde Tem - Light trapping, thin flm, silicon solar cells,
antirefection coating.
I. INTRODUCTION
Single junction, crystalline silicon (c-Si) solar cell, in spite
of their relatively high cost (�$5.50 per watt) has captured
more than eighty percent of the current solar cell market, due
to their relatively high efciency. But, cost is the main
impediment for solar cells to capture a larger market share.
Thus, identifing and demonstrating practical schemes to
achieve device efciencies comparable to c-Si while reducing
manufacturing costs is considered the greatest challenge that
needs to be overcome. The high cost of c-Si structures
originates on its poor infared absorption that arises fom its
indirect band gap, which has driven the geometry of wafer
based silicon solar cells to include a c-Si active layer of
thickness 180-300 f.m. This relatively thick layer is employed
as the means to absorb light effectively and, hence, increase
device efciency, but it also accounts for nearly forty percent
of the total device cost. In order to address the challenge of
bringing the cost down while attempting to achieve reasonable
effciencies, thin flm solar cells have been extensively
characterized mostly because they are considered an
alterative low cost photovoltaic choice of, approximately,
less than $ 1 per watt. However, thin-flm structures routinely
exhibit a lower efciency than their traditional wafer based c
Si counterparts. Thus, to increase the optical absorption of
thin-flm solar cells, various geometry confgurations including
randomly [ 1] or periodically [2-8] textured surfaces,
nanoparticle arrays and plasmonic structures [9- 12] have been
intensively studied. Furthermore, noble metal nanopatricles
978-1-4673-0066-7/12/$26.00©2011 IEEE
like gold (Au), silver (Ag) etc. have been used for light
trapping purpose in thin flm solar cells [9, 10]. Metal
nanoparticles interact strongly with visible and infared
photons due to the excitation of localized surface plasmons
(LSPs). LSPs are the collective oscillation of fee electron in
the metal nanoparticles. The strongest optical interaction
occurs at a resonance, with the resonance condition being a
fnction of nanopaticles size, shape and type of metal, as well
as the local dielectric environment. Upon excitation the LPSs
can decay radiatively, resulting in scattering, or non
radiatively, resulting in absorption. The resonance scattering
peak can be tune by optimizing the size of the particle and by
changing surrounding medium. This approach has the potential
to confne and guide the incident radiation into the substrate.
In this letter, we studied the localized surface plasmon effect
of the Au nanoparticles deposited on the SiNH array textured
surface for the thin flm solar cells application.
II. THEROY AND SIMULAITON MODEL
Fig. 1 depicts the schematic of the SiNH arrays textured
surface with the periodicity P, diameter D and nanohole depth
H for the optical simulation. To include the localized surface
plasmon effect, Au nanoparticles are kept on the surface of the
SiNH structure. This can be done experimentally by the
thermal dewetting of thin gold flms deposited on the SiNH
structure as in [ 13]. The plane electromagnetic wave is
assumed to be normally incident on the sample. The energy
(a)
PML
H --
j
-- P
PML
(b)
Fig. 1. (Color online) Three dimensional structure of SiNH arrays
textured surface. (b) Two dimensional unit cell structure of SiNH
arrays textured surface with periodicity P, diameter D and nanohole
depth H.
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